A couple of books have caught my eye during the year and have naturally made their way into my Christmas wish list (and some I’ve already ordered myself). Please let me know if there are books you belive should be on this list that I have missed.

Culinary Reactions: The Everyday Chemistry of Cooking
by Simon Quellen Field
288 pages

The back cover states “When you’re cooking, you’re a chemist!”. I couldn’t agree more and figured this was a book for me. I already have my copy in front of me and see there are many interesting observations and experiments described.

Heston Blumenthal at Home
by Heston Blumenthal
408 pages

The Family Meal: Home Cooking with Ferran Adria
by Ferran Adrià
384 pages

Ferran and Heston have jumped onto the cooking-at-home-with-great-chefs waggon. They’d be more than welcome to come and cook in my kitchen, but until that happens I’ll let their books inspire me. An important thing about these books is that, given their close collaboration with scientists, I have a high expectation that the advice given in all recipes should be scientifically sound (which of course is not the case for many other cook books).

Neurogastronomy: How the Brain Creates Flavor and Why It Matters
by Gordon M. Shepherd
288 pages

I stumbled across this one by chance. It looks like a “must have” too me, and my copy is already on its way. In an interview with Salon, the author Gordon M. Shepherd, a professor of neurobiology at the Yale School of Medicine, says that:
“I began to realize that increasingly smell was for sensing the flavor of food. It goes almost unrecognized as we eat our food because we think it all comes from taste in our mouths. The more research that I did on flavor, the more I realized that the sense of smell was the dominant sense in flavor — and that we are almost totally unaware of it.”

The Oxford Companion to Beer
edited by Garrett Oliver
960 pages

Having ventured into brewing I found this book quite irresistable!

The Kitchen as Laboratory: Reflections on the Science of Food and Cooking
edited by Cesar Vega, Job Ubbink and Erik van der Linden
336 pages

I’ve mentioned this book previously. With 35 essays covering a range of topics this should be of interest to many Khymos readers!

Apart from these books we just have to face it: there’s no way around Modernist cuisine. If you don’t own a copy yet I’m quite sure it still sits there on the top of your wish list. And – if you happen to read Swedish – I would highly recommend the recently published book Matmolekyler (“Food molecules”) by Malin Sandström and Lisa Förare Winbladh (also check out their blog blog with the same name – also in Swedish).

Talking to a friend last year who is an avid home brewer made me realize how little I knew about beer and brewing. Inspired by what I learnt from the conversation I started reading Palmer’s How to brew which is essential for starters, but soon I also turned to Brigg’s Brewing – Science and practice and Priest’s Handbook of Brewing which are more rewarding if you’re a scientist. The first two steps in brewing beer – mashing and wort boiling – are really quite sophisticated extractions. And there is a lot of chemistry involved, so brewing beer seemed to me like an obvious extension of all my other interests. This is also the reason why I wanted to include a post about brewing in the Wonders of extraction series. The pictures for this blog post were taken as I brewed and bottled my latest batch, an American India Pale Ale.

Having read quite a lot about beer I soon found myself in the kitchen brewing my very first German wheat beer in August last year. I had decided that to familiarize myself with brewing I would try to brew with whatever equipment I had available in the kitchen. Mashing and lautering was done with a pasta strainer(!), and I boiled the wort in the largest pot I could find. While doing this it became very clear to me that these steps can be viewed as “reactive extractions”. Something is extracted and then something more happens! Given the simple method and equipment used I was totally amazed by the end result. And I quickly decided that this would not be my last batch of beer. After hours or reading (and making an important decision that I would like to spend my time brewing, rather than building the equipment) I finally settled with a Speidel Braumeister. This is a compact RIMS (Recirculating Infusion Mash System) type brewery system where a pump forces the wort upwards through the malt bed (different from a conventional RIMS system where the wort is allowed to drain through the malt bed by gravity). The picture below probably explains more than countless words.

The Speidel Braumeister is a compact RIMS type brewing system. During mashing a malt pipe is inserted. A metal screen and filter cloth at both ends of the malt pipe hold the malt in place. A pump forces the wort upwards through the mash (bottom left). After mashing the malt pipe is lifted out to allow the wort to drip of (bottom middle). Extra water may be added to rinse out remaining wort. The malt pipe is removed prior to the wort boiling (bottom right). Illustrations taken from www.speidel-braumeister.de

What really attracted me to brewing is that the range of ingredients available to professional brewers is also available to home brewers. And while a commercial brewery will do what it can to cut costs, opting for cheaper ingredients whenever possible, the money spent on malt, hops and yeast doesn’t really matter that much for the home brewer. As a result one can actually brew some very nice beers at home. And a much larger range of beers than is available in your next door shop. I believe this is quite different from what is the case for home brewing of wine (at least in Norway where fresh grape juice in those quantities is not available).

The extraction of sugars from malted barley is termed mashing. During mashing one utilizes the enzymes naturally present in grains to break down the starch to fermentable sugars (meaning sugars that the yeast can convert to alcohol). It sounds simple, but the process involves a number of enzymes with different temperature and pH optima. And one needs to do a couple of tricks for the enzymes to appear, so I will start with a brief introduction to malting (but feel to skip this and continue reading about mashing further down).

Malting
When a barley seed is wetted it will start to germinate. The release of the plant hormone gibberellic acid in the seed embryo sets of the synthesis of proteins capable of breaking down starch to sugar which will be needed for the seed to grow. These proteins are called enzymes, and they are extremely efficient at breaking down starch to sugar. After a couple of days the sprouted grain is air dried. As the water content decreases a second plant hormone, abscisic acid, is released. The effect is the opposite of gibberellic acid, and the synthesis of further enzymes is halted. The lowered water content also stops the enzymatic breakdown of the starch. The air dried green malt as it is now called is further kiln dried. The small amount of liberated sugar alongside the proteins allows for the Maillard reaction to proceed if the conditions are right, resulting in characteristic malt and caramel flavors as well as colors ranging from golden to brown and almost black. The darker the color of the malt, the less will be left of the enzymes required for starch hydrolysis (but this is usually not a problem as only a relatively small amount of very dark malt is used). Some enthusiasts malt their own barley, but most home brewers buy whole grain malt.

The hopper of my malt mill filled with ~5 kg malt is ready for some action (top left). As the grains pass the two rollers (bottom left) the malt is carefully crushed (bottom right). If crushed too fine the result is a “stuck mash”, if crushed too coarsely less sugar will be extracted and the yield drops.

Bottom screen and filter cloth inserted into the malt cylinder (top left) which is then lowered into the water filled brewing pot, crushed malt is then poured into the malt cylinder (top right), covered with a filter cloth (bottom left) and a metal screen (bottom right).

Mashing
The malt now contains starch as well as the enzymes required to break down the starch. When water is added and the temperature brought up to around 65-67 °C the enzymes start doing their job which is to break down the starch to sugars. This step is called mashing. Several enzymes are at play, but I’ll focus on the two most important: alpha-amylase and beta-amylase. Alpha-amylase is more temperature stable, attacks and breaks up the starch polymer at random places, resulting in smaller starch molecules known as dextrins. Only a very small fraction of the starch is converted to fermentable (= usable for the yeast) sugars by alpha-amylase. Beta-amylase on the other hand is less temperature stable but breaks down starch to maltose which is fermentable. By carefully choosing the mashing temperature the relative activity between alpha- and beta-amylase can be fine tuned. Mashing at 64-65 °C favors beta-amylase which yields a wort higher in fermentable sugars, resulting in a beer which is thinner, drier, higher in alcohol and has a lower final gravity. Mashing at 68-69 °C favors alpha-amylase which yields more dextrins which are not fermentable, resulting in a beer with more body which is sweeter, lower in alcohol and has a higher final gravity (i.e. residual “sugar” content). This may be confusing but trust me – it’s even more confusing when John Palmer tries to explain it with a garden allegory! I encourage you to check out the figure below which may help clarify things.  After mashing is complete the temperature is increased to 78 °C to inactivate the enzymes. The malt pipe is then pulled up to allow the wort contained in the malt bed to run off (termed lautering). The malt bed may be washed with 78 °C water (sparging) to increase the yield.

The wort is circulated upwards through the malt bed throughout the mashing time. At first the wort is very cloudy (top left) due to the fine particles from the crushing. The malt bed acts as a huge filter which helps remove particles, yielding a clear wort (top right). The time and temperature steps are controlled by a PID (bottom left). After mashing the malt cylinder is pulled up, the wort is allowed to run off (termed lautering) and the malt bed may be washed with water (sparging). The malt that remains is known as wet distillers grain (bottom right) and does wonders to your compost! Or you can use some of it for baking a special bread called treberbrot (named after the German word for spent grain).

If the extractable yield of a malt was 100% and the mash efficiency was 100% 1 kg malt would yield 1 kg of sugar in the mash. However, the extractable yield for a pale malt is about 80% (the hulls for instance are not extractable), and in my last brew I reached a mash efficiency of 78%. In effect I got approximately 624 g of sugar for each kg of malt.

Wort boiling
After mashing and lautering the wort is heated further and kept at a rolling boil for about one hour. There are several reasons for this. First the mashing enzymes are destroyed. Another one is to sterilize the wort (i.e. kill off unwanted bacteria and yeasts) prior to the following fermentation. Furthermore the boiling will allow some unwanted volatiles such as dimethyl sulfide to escape. The boiling will also facilitate the precipitation of proteins, resulting in a clearer beer. But perhaps most important for the resulting taste of beer is the addition of hops to the boiling wort. Hops are a kind of flowers that impart a bitter taste and in some cases also a significant aroma to beer. The bitterness balances the sweet taste of the wort, and the hops also stabilize and increase the shelf life of beer due to a mild antibiotic effect against bacteria that could otherwise ruin the beer.

Hops are typically added as whole cones or pellets as shown here. The pellets are crushed hop flowers that have been compressed for easier addition. Once added to the wort the pellets fall apart. The larger surface area of the fines results in a faster extraction of the alpha acids.

The hop cones contain alpha acids which are not particularly water soluble, and in fact not very bitter either. But when boiled they undergo a chemical change which makes them more bitter, the so called isomerization (shown below). Hops that are added for bittering of beer are typically added to the wort once it starts to boil as the extraction and isomerization processes takes some time. The extraction of alpha acids and the isomerization process are well studied and brewers can accurately predict and design the bitterness of a beer using online calculators. Required input data are wort volume, wort gravity (i.e. sugar content), alpha acid content in the hops and boil time as well as whether the hops are added as whole flowers or as fines compressed to a pellet. The hop bitterness is expressed in International Bitter Units (IBU), typically ranging from light lagers or wheat beers with 5 IBU up to India Pale Ales with 100 IBU or more. Those with access to a spectrophotometer can measure an approximate IBU of a beer by recording the absorbance at 275 nm and multiplying the number by 50 (IBU = A₂₇₅ x 50).

In addition to alpha acids hops also contain essential oils, some lighter, more volatile (primarily terpenes such as myrcene, linaol, geraniol, limonene, terpineol etc. – typically with a citrusy, green, grassy, floral aroma) as well as some heavy, less volatile oils (humulene, caryophyllene, farnesene – typically with a woody, spicy aroma). When smelling fresh hops it’s primarily the essential oils that make up the aroma. The majority of volatiles are lost from the boiling wort due to evaporation. However, if hops are added towards the end of the boil the less volatile oils will remain in the wort and in the resulting beer and impart a significant hop aroma to the beer (not to be confused with the bitter taste which results from prolonged boiling of hops). In some cases hops are even added to the wort during of after fermentation, so called dry hopping. This allows the extraction of the lighter volatile essential oils in the hops. In order to capture the lightest volatile oils it’s important to use fresh hops (i.e. hops that have not been dried). To complicate matters further many of these essential oils are quite reactive towards oxygen, and if digging deeper into the molecules behind a “hoppy” aroma one will find several oxidation products of the essential oils.

Here I should add that chefs probably could learn something from the early and late addition of hops to the boiling wort. I have a feeling that the early vs. late addition of spices and herbs has not yet been explored sufficiently. And just like the same hop contributes different “fractions” of its flavor depending on when it is added I also think that spices and herbs could contribute a broader range of aromas if they were not added all at once. I would be very interested in hearing your opinions on this! And hereby I also share an idea for a nice science project: Boil herbs/spices, take samples regularly and see how concentration changes with time. When does it reach a maximum? This would be very useful information for chefs!

The wort is boiled (top left) for several reasons, one is to extract and isomerize alpha-acids from hop cones into iso-alpha-acid which provide the important bitterness to beer. After boiling cold water is passed through a copper spiral (top right) to rapidly cool the wort (bottom left). After cooling the gravity (i.e. density) of the wort may be measured with a hydrometer (bottom right).

Towards the end of the wort boil some brewers also add some Irish moss to help clarify the wort. Interestingly this moss should be well known to the readers of Khymos, albeit in a slightly different form – namely as a white powder sold under the name carrageenan!

Dry Irish moss contains more than 50% of the polysaccharide carrageenan. When used in brewing the moss is wetted and allowed to hydrate before it is added added to the boiling worth the last 10-15 min.

The rest of the brewing process does not involve extractions, and hence is not the main focus of this blog post. But I’ve included some pictures to give you an idea of the different steps:

The cooled wort is sprinkled (top left) into the fermentation bucket to expose it to oxygen. For extra oxygenation an aquarium air pump can also be used to aerate the wort, resulting in some foam (bottom left). The added oxygen allows the approximately 100 billion yeast cells (top right) to grow/multiply before they move into anaerobic mode to produce ethanol from the wort sugars (primarily maltose). Proteins and hop residues are carefully left behind in the boiling vessel (bottom right).

Clean bottles are covered with aluminum foil prior to dry sterilization (top left). The fermented (and in this case dry hopped wort) is siphoned (top right) into a second bucket where it is mixed with the priming sugar need for bottle carbonation. The bottling device used here (bottom left) has a small valve which only opens once the bottom of the bottle presses against it, thereby reducing foaming during bottling. Labels are glued onto the bottles with milk.

After a minimum of 1-2 weeks bottle fermentation the American India Pale Ale is sufficiently carbonated for the very first tasting!

Previous blog posts on the Wonders of Extraction
Wonders of extraction: Water
Wonders of extraction: Ethanol
Wonders of extraction: Oil
Wonders of extraction: Espresso (part I) (sorry – no part II yet…)
Wonders of extraction: Pressure

Wheat beers such as hefeweizen, weissbier and wit are all light beers made from a mix of malted barley and wheat. In southern Germany the typical hefeweizen is fermented with a non-flocculating yeast, and it is not filtered before bottling. This gives the beer a yeasty, bread like flavor accompanied by aromas reminiscent of banan, cloves (we’ve encountered that combo before), coriander and citrus. I’ve just begun to read up on brewing and my first batch of a partial mash hefeweizen is bubling along. As I pitched the liquid hefeweizen yeast into the wort I decided to keep a tiny amount for baking. If hefeweizen beer is reminiscent of bread, why not use the yeast for making bread? In particular I was curious whether some of the aroma top notes characterizing hefeweizen beer would stand out in bread made using the same yeast.

The specific yeast I used was obtained as a liquid suspension from White labs. Their hefeweizen yeast strain (catalogue number WLP300) is identical to Weihenstephan 68. And in case you didn’t know – Weihenstephan is the world’s oldest brewery. Wine yeast is the same as beer yeast (or ale yeast to be more precise) and baker’s yeast – and they are all known under the latin name Saccharomyces cerevisiae (which literally translates to something like a “beer producing sugar munching fungi”). Why bother if they are all the same yeast you may ask. It’s a good question, but despite the common name they are different isolates with very different properties. They certainly have a lot in common: in the presence of air they consume sugars to grow, and in a closed environment without access to air the consumed sugars are instead converted to alcohol and carbon dioxide. But besides this main reaction there are hosts of other enzymes present that produce higher alcohols, aldehyes, acids, esters – all of them volatiles compounds that contribute significantly to flavor. And this is typically where the isolates of S. cerevisia differ. There’s a mind boggling array of beer yeasts available. Take a look at the yeast catalogues of White labs, Wyeast or Fermentis to get an idea of the many yeast strains that are available (note that the lists includes both ale yeasts S. cerevisia which are top fermenting and lager yeasts S. carlsbergensis which are bottom fermenting, meaning that the yeast sinks to the bottom when the job is done). And if this doesn’t impress you – consider the fact that there are thousands of S. cerevisia isolates available from culture collections around the world (ATCC and CBS are among the largest – do a search for S. cerevisiae at ATCC and it tells you to narrow your search because there are more than 5000 hits!).

Apart from the specific strain used the fermentation conditions will also greatly influence the volatile profile: temperature, time, pH, micro and macro nutrients present, and the sugars available all have their say. A general advice for artisan breads is to use only a small amount of yeast (2-3 g) to start with and give the dough plenty of time to develop and rise. This gives a richer flavor compared to using 50 g of fresh yeast to obtain a rapid rise. Since I only started with about a 1/4 teaspoon of yeast slurry I first had to let the yeast grow and multiply. Since S. cerevisiae needs oxygen to grow I added 50 g of water to the yeast slurry and then used a hand mixer to whip in air for a minute or so before adding 50 g of flour. I left the pre-ferment (aka poolish or biga) on the benchtop and the next day there was plenty of bubbling activity. I added more water, whipped in more air with a hand mixer and once again added as much flour as water. This yielded an active starter and all was set for baking.

Hefeweizen bread

Pre-ferment (evening before baking day):
65 g starter (100% hydration)
110 g water
110 g all purpose wheat flour

Baking day:
285 g starter (100%) from day before
466 g water
250 g emmer
485 g all purpose wheat flour
12 g salt

Total dough weight: 1498 g
Hydration: 69%

Add water to starter and incorporate air with a hand mixer to give the yeast a good start. Mix in the flour, cover and leave at room temperature. Next day, mix all ingredients and leave to rise (this may take 1-3 hours). Divide in two, fold over repeatedly and shape into boules. Leave to rise. Preheat oven to 250 °C. Use a baking stone, and generate some steam in the oven during the first 10 min (see picture below). After 10 min, turn down to 220 °C and bake until crust has a nice golden crust.

My current steam setup: I use ice cubes since this prevents a sudden gush of steam towards my hands. The stones serve as a heat reservoir ensuring that the ice cubes melt and evaporate within a couple of minutes. To cope with the heat shock I use a plate of stainless steel to hold the stones. After 10 min I open the oven door to vent out steam and remove the plate with the stones to allow an even heating (no reflection!) of the baking stone from below.

So how did it taste? The bread tasted excellent, but to be honest – I couldn’t detect any aroma that I can’t get using conventional baker’s yeast. The reason for this is probably that other flavors (i.e. from the flour, the baking process etc.) dominate. Another factor is that bread is only fermented for a couple of hours compared to several days for beer. This simply doesn’t give enough time for significant concentrations of the volatile compounds to develop. Lastly, the baking process will drive off the most volatile compounds. Nevertheless, I would still encourage you to try this! I didn’t get the result I hoped for (I was a little optimistic), but it’s a fun experiment to do, especially if you have some yeast left over from beer brewing anyway.

I am by no means the first to try this. But it seems that results are mixed. Some complain about slow rising doughs. But there are also many misconceptions around. One is that some yeasts produce more alcohol whereas other yeasts produce more gas. As long as we’re talking about anaerobic fermentation of sugar to ethanol and carbon dioxide this is plain wrong as ethanol and carbon dioxide are produced in a 1:1 ratio. There is also some confusion with regards to the naming (i.e. beer yeast, ale yeast, brewer’s yeast, baker’s yeast etc. – when all in fact are the same yeast).

Since the bread came out just like bread made with conventional baker’s yeast it’s fair to turn the question around: Do the different beer yeasts really make a difference? I did a quick search in the scientific littereature and found a couple of papers that study the effect of yeast strains on the formation of volatile compounds in beer and wine:

Yeast Influence on Volatile Composition of Wines
Ester Concentration Differences in Wine Fermented by Various Species and Strains of Yeasts
Synthesis of volatile phenols by Saccharomyces cerevisiae in wines
Function of yeast species and strains in wine flavour
Expression Levels of the Yeast Alcohol Acetyltransferase Genes ATF1, Lg-ATF1, and ATF2 Control the Formation of a Broad Range of Volatile Esters

I haven’t had the opportunity to dig really into this, but from the abstracts it definitely seems to be the case that the selection of yeast strains also play a vital role in the resulting aroma profile of the beer.

Oh yeah, one more thing: For this particular bread I used emmer from a local mill, Holli Mølle, specializing in ancient cereals. Emmer (aka farro) doesn’t form as much gluten as conventional wheat (I tried making a 100% emmer no-knead bread which tasted nice but was a fiasco shape wise…), but it does lend a light greyish/brown color to the crumb and also gives the bread a richer flavor. But the use of emmer is of course not a pre-requisite if you want to bake with beer yeast

Looks good and tastes good!

Here at Khymos I aim to cover things related to food and chemistry, and as I stumbled over a periodic table of cupcakes (with clickable “elements” linked to recipes) I couldn’t resist to dig a little deeper. And look what I found! The periodic table of elements is iconic, but the periodic table has also become an organizing metaphor for all sorts of things, including food. The Internet database of periodic tables holds more periodic tables than you could ever dream of, but it’s not complete – at least not with regards to food. Here are the food related periodic tables that I’ve been able to find. Fun? Yes! Useful? No, not really At the end of the post I’ve also included examples of how the real periodic table of elements can be illustrated in a more or less edible fashion. All images are linked to the page where I found them. Are you aware of other periodic tables of food? Please let me know and I’ll include them in this post.

Available as a poster. HighRes available here.

Available as a poster

In case you wondered, it’s a periodic table of breakfast cereals!


HighRes flash version

Condiments that periodically go bad

Cupcakes – what else! And each “element” is linked to a recipe. Very well made!

Period table of food from Disneyland in Los Angeles (Photo: Martin Lersch). Click for a larger image.

Available as a poster

Available as a poster

Available as a poster

Available as a poster

HighRes version available

Two cropped scans available from Slashfood. Original was published in “Simple Life” fall 2006.

Available as a poster

Available as a poster

The menu at “Miracle of Science Bar & Grill” in Boston is a periodic table painted on the wall. More info at the C&EN blog. Photo: Scott Beale/Laughing Squid

Periodic table of preserves. Full resolution view available through this preview (browse to page 22 of the preview, book pages 48-49).

The real periodic table of elements represented in food
If you think fitting some kind of food into a periodic table is stretching a little too far, why not make an edible version of the real periodic table? In the process you may even learn the name of some elements

Photo by melpenguin

A nice idea for Halloween?

As the name suggests, the TGIF posts are a little less serious than what I otherwise post here at Khymos. I hope you enjoy it

As malt was one of the foods to pair for this month’s TGRWT I decided to do something with beer. I first considered making a beer gel since the Alinea book has a nice recipe (with potassium citrate and kappa carrageenan – I included the recipe in the hydrocolloid recipe collection), but since I didn’t have carrageenan at hand I decided to try a sorbet. A quick search gave me 4 recipes (links in the table below) and in order to compare these I decided to calculate sugar/beer and sugar/liquid ratios as these are quite crucial in order to obtain the desired consistency of a sorbet. The results are shown in the table below.

reference	beer mL	water mL	sugar g	sugar/liquid	sugar/beer
Recipe 1	330	257	340	0.58	1.03
Recipe 2	1360	50	383	0.27	0.28
Recipe 3	310	567*	311*	0.35	1.00
Recipe 4	710	370	335	0.31	0.47

* Recipe 3 uses milk instead of water. There are also 2 oz liquid glucose which I’ve not included since there is no information about the concentration.

I was surprised to find such a great difference between the recipes with regards to sugar and alcohol content. The large ranges for sugar/liquid and sugar/beer ratios (0.27-0.58 and 0.28-1.03 respectively) suggest to me that the recipes are a little arbitrary. Unfortunately I wasn’t able to find tables plotting out the the combined effect of sucrose and alcohol on sorbets – perhaps you know about such a resource? (I tried googling for ethanol, sucrose and freezing point depression without success) In the end I figured recipe 4 seemed most reasonable and scaled it down a little. I had planned on using lemon juice, but there were no lemons left in the fridge so I went with balsamic vinegar instead.

Beer sorbet
150 mL water
140 g sugar
0,85 g gelatin (1/2 sheet, 0,14%)
10 mL balsamic vinegar
300 mL beer (pilsner type, 4.5% alcohol)

Bring water and sugar to boil and stir until sugar has dissolved. Remove from heat, add bloomed gelatin. Add beer and vinegar. Cool and freeze. If freezing without an ice cream maker, mix well once frozen and freeze again. I served it with diced galia melon, marinated in soy sauce and sugar.

Scientific considerations: I intentionally did not boil the beer to avoid oxidation and an sulfurous flavor, and it’s probably also advisable to let the sugar/gelatin mixture cool down before adding the beer. I’m not particularily fond of stale beer, and not heating the beer is a way to avoid this. To reduce syneresis and inhibit formation of large crystals I added a little gelatin to the recipe (locust bean gum or agar/xanthan will also do the trick). The consistency was perhaps a bit too soft, but the following numbers should be a useful guide when adjusting the recipe.

Final sugar concentration: 23%
Final alcohol concentration: 2.25% (vol%)
Final gelatin concentration: 0.14%

Creamy texture after second freezing!

Verdict: The beer sorbet was a pleasant surprise! Very creamy texture, perhaps a little on the soft side, but the gelatin helped maintain structure. The flavor was sweet, savory and acidic at the same time. The melon with soy sauce however was not so great. The leftover beer sorbet will be served with lemon and lime marinated melon in stead of the soy sauce

This month’s round of the food blogging event They go really well together (TGRWT) will be hosted by Rob over at The Curious Blogquat. We’ve now come to TGRWT #14 and the foods to pair this time are malt and soy sauce (soya sauce). Regarding the malt you are free to choose whatever form you like – you can use malt extract, powdered malt, grains or even beer if you like. As usual you can cook from an existing recipe or come up with your own. The deadline for submissions is February 1st and you can find more information on how to participate in the announcement post.

And do not forget to check out the roundup of the delicious cocoa and caraway recipes from TGRWT #13.

BTW: Tomorrow I’m heading of for the flavor pairing seminar “The Flemish Primitives” in Bruges, Belgium. I’m really excited about that and I promise I’ll return with an extensive report! From the homepage I see that Sang-Hoon Degeimbre has chosen Leffe (a Belgian beer) and who knows – maybe he’ll combine it with soy sauce

As shown in the figure, the radical reacts with sulfur containing proteins, thereby forming a thiol called 3-methylbut-2-ene-1-thiol or just MBT for short. The amazing thing about this compound is that we can smell it at concentrations as low as a few parts per billion (ppb). The perhaps not-so-amazing thing is that this compound gives beer a “skunky” aroma. Obviously one would want to avoid this, and that’s why beer is sold in dark brown glass bottles that act as the beer’s own sunglasses. Canned beer of course will not go skunky (well not until it’s poured into a glass and served outside in bright sunlight – that will turn any beer skunky within minutes).

Unfortunately however, not all beer is sold in dark bottles! One well known brand is shown in the picture below…

And yes – as you might have figured out, 3-methylbut-2-ene-1-thiol is present in Corona beer (and other brands sold in clear bottles, to a lesser extent MBT is also found in green bottled beer). For some references to “skunky” off flavours in beer check out these links: here, here and here. The ubiquitious slice of lime served with Corona beer is nothing but clever marketing since it helps camouflage the smelly thiol formed! (but how well does lime actually camouflage the thiol aroma?)

The take home message is: keep your olive oil, milk, butter and beer away from sunlight!