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	<title>Khymos &#187; carbonic acid</title>
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	<link>http://blog.khymos.org</link>
	<description>- dedicated to molecular gastronomy</description>
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		<title>Carbonated fruit the iSi way</title>
		<link>http://blog.khymos.org/2007/04/09/carbonated-fruit-the-isi-way/</link>
		<comments>http://blog.khymos.org/2007/04/09/carbonated-fruit-the-isi-way/#comments</comments>
		<pubDate>Mon, 09 Apr 2007 00:15:41 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[equipment]]></category>
		<category><![CDATA[experiments]]></category>
		<category><![CDATA[fun with food]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[tips & tricks]]></category>
		<category><![CDATA[bubbles]]></category>
		<category><![CDATA[carbon dioxide]]></category>
		<category><![CDATA[carbonated fruit]]></category>
		<category><![CDATA[carbonation]]></category>
		<category><![CDATA[carbonic acid]]></category>
		<category><![CDATA[CO2]]></category>
		<category><![CDATA[iSi]]></category>
		<category><![CDATA[kitchen physics]]></category>
		<category><![CDATA[molecular mixology]]></category>
		<category><![CDATA[physics]]></category>
		<category><![CDATA[sparkling]]></category>
		<category><![CDATA[techniques]]></category>
		<category><![CDATA[tools]]></category>
		<category><![CDATA[whipper]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/04/09/carbonated-fruit-the-isi-way/</guid>
		<description><![CDATA[I blogged about carbonated strawberries some while ago. Those were made using dry ice which unfortunately is not always easy to get hold of. Last week however I bought a iSi Gourmet Whipper &#8211; one of those Ferran Adria uses to make foams/espumas. I plan to experiment with that as well, but the first thing [...]]]></description>
			<content:encoded><![CDATA[<p>I blogged about <a href="http://blog.khymos.org/2006/10/22/carbonated-strawberries/">carbonated strawberries</a> some while ago. Those were made using dry ice which unfortunately is not always easy to get hold of. Last week however I bought a <a href="http://www.amazon.com/exec/obidos/ASIN/B0006FRXNG/kjemiihverdao-20">iSi Gourmet Whipper</a> &#8211; one of those Ferran Adria uses to make foams/espumas. I plan to experiment with that as well, but the first thing I decided to prepare was carbonated fruit. In fact this is a safe way (the only?) to make carbonated fruit at home using a pressurized container. </p>
<p><img src='http://blog.khymos.org/wp-content/2007/04/isi-whipper.jpg' alt='isi-whipper.jpg' /></p>
<p>The instruction booklet which comes with the iSi Gourmet Whipper only mentions <a href="http://www.amazon.com/exec/obidos/ASIN/B00007JXR5/kjemiihverdao-20">cream chargers</a> (filled with N<sub>2</sub>O, dinitrogen oxide), whereas <a href="http://www.amazon.com/exec/obidos/ASIN/B00007JXR8/kjemiihverdao-20">soda chargers</a> (filled with CO<sub>2</sub>, carbon dioxide) are not mentioned (I guess the opposite is true for the <a href="http://www.amazon.com/exec/obidos/ASIN/B0002COPS4/kjemiihverdao-20">iSi Siphons</a>?). This is quite amazing actually! Luckily however the cream and soda chargers are exactly the same size and both hold 8 g of gas. So it should be possible to make carbonated fruit with any of the iSi whippers (<a href="http://www.amazon.com/exec/obidos/ASIN/B00007JXR1/kjemiihverdao-20">cream</a>, <a href="http://www.amazon.com/exec/obidos/ASIN/B0006FRXD6/kjemiihverdao-20">easy</a>, <a href="http://www.amazon.com/exec/obidos/ASIN/B00007JXQW/kjemiihverdao-20">gourmet</a>, <a href="http://www.amazon.com/exec/obidos/ASIN/B000FDN1TE/kjemiihverdao-20">dessert</a>, <a href="http://www.amazon.com/exec/obidos/ASIN/B000KIP63S/kjemiihverdao-20">thermo</a>) or siphons available.</p>
<p>Here&#8217;s how you proceed:</p>
<ol>
<li>Fill you iSi whipper (or siphon) with fruit, preferably fruit which has a cut, wet surface to allow the carbon dioxide to dissolve in the water/juice.</li>
<li>Screw on top securly</li>
<li>Charge with one soda charger (two if you have the 1 L whipper)</li>
<li>Leave in fridge over night</li>
<li>Release pressure with valve (Important!)</li>
<li>Unscrew top and serve <em>immediately</em>!</li>
<li>Enjoy!</li>
</ol>
<p><img src='http://blog.khymos.org/wp-content/2007/04/carbonated-grapes.jpg' alt='carbonated-grapes.jpg' /><br />
<em>This is what carbonated grapes look like. As you see, I decided to cut the grapes in to halves.<br />
</em><br />
<img src='http://blog.khymos.org/wp-content/2007/04/carbonated-grapes-closeup.jpg' alt='carbonated-grapes-closeup.jpg' /><br />
<em>Notice how they sizzle! </em></p>
<p>A quick recap of the chemistry: cold water dissolves more CO<sub>2</sub> than tempered water, that&#8217;s why we leave it in the fridge. Also, remember that it takes some time for the carbon dioxide to dissolve in water, therefore it&#8217;s better not to be in a hurry. A quick calculation of the pressures gives the following: Both gases have molecular weights of 44 g/mol, so 8 g of gas corresponds to 0.1818 moles or 4.1 L at 25 °C and 1 atm pressure. The volume of the chargers is 0.01 L which gives an initial pressure in the chargers of impressive 445 atm! With an approximate volume of 0.7 L this gives a pressure (in an empty whipper) of nearly 6 atm &#8211; the same as in a bottle of champagne. However once you add water, the equilibriums will change and the pressure in the head space will drop. Anyone who remembers how to calculate the head space pressure at equilibrium if the container is filled with 0.5 L of water and cooled to 4 °C?</p>
<p>I&#8217;ve done some googling and there is also <a href="http://ideasinfood.typepad.com/ideas_in_food/2006/06/cherry_soda.html">some</a> <a href="http://ideasinfood.typepad.com/ideas_in_food/2006/07/smoked_maple_sy.html">mention</a> of making carbonated fruit with an iSi whipper over at Ideas in food.</p>
<p>(The word play in the title works better for those with a mother tongue where iSi would be pronounced just like &#8220;easy&#8221;!)</p>
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		</item>
		<item>
		<title>Carbonated strawberries</title>
		<link>http://blog.khymos.org/2006/10/22/carbonated-strawberries/</link>
		<comments>http://blog.khymos.org/2006/10/22/carbonated-strawberries/#comments</comments>
		<pubDate>Sun, 22 Oct 2006 18:10:22 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[experiments]]></category>
		<category><![CDATA[fun with food]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[science]]></category>
		<category><![CDATA[carbon dioxide]]></category>
		<category><![CDATA[carbonated fruit]]></category>
		<category><![CDATA[carbonic acid]]></category>
		<category><![CDATA[CO2]]></category>
		<category><![CDATA[dry ice]]></category>
		<category><![CDATA[equilibrium]]></category>
		<category><![CDATA[strawberry]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2006/10/22/carbonated-strawberries/</guid>
		<description><![CDATA[Here&#8217;s some pictures of an experiment I did with strawberries and dry ice (solid carbon dioxide). Dry ice is frozen carbon dioxide which holds a temperature of -78 °C. What is fascinating is that dry ice does not melt &#8211; it sublimes, which means that it turns directly into carbon dioxide gas. The idea was [...]]]></description>
			<content:encoded><![CDATA[<p>Here&#8217;s some pictures of an experiment I did with strawberries and <a href="http://www.howstuffworks.com/question264.htm">dry ice</a> (solid carbon dioxide). Dry ice is frozen carbon dioxide which holds a temperature of -78 °C. What is fascinating is that dry ice does not melt &#8211; it <a href="http://en.wikipedia.org/wiki/Sublimation_(physics)">sublimes</a>, which means that it turns directly into carbon dioxide gas.</p>
<p>
The idea was to create a carbonated fruit which gives a sparkling sensation in the mouth. I have used strawberries, but any juicy fruit with a moist surface could be used. Water melons would be perfect!</p>
<p>The chemistry explained in simple terms:</p>
<p><img id="image27" src="http://blog.khymos.org/wp-content/2006/10/co2.jpg" alt="co2.jpg"/></p>
<p>A schematic drawing of the container:</p>
<p><img id="image23" src="http://blog.khymos.org/wp-content/2006/10/strawberry-dryice.jpg" alt="strawberry-dryice.jpg"/></p>
<p>To prevent the plate from touching the dry ice (which would cause the strawberries to freeze), I put in a wooden triangle first.</p>
<p><img id="image24" src="http://blog.khymos.org/wp-content/2006/10/p7110004.JPG" alt="p7110004.JPG"/></p>
<p>
Put the plate with strawberry halves on top of the wooden triangle. Cover with a kitchen towel (do NOT cover with a tight fitting cover &#8211; remember that as CO<sub>2</sub> sublimes, it expands, and this would create a huge pressure ultimately resulting in an explosion), and leave for 30 minutes.</p>
<p><img id="image25" src="http://blog.khymos.org/wp-content/2006/10/p7110005.JPG" alt="p7110005.JPG"/></p>
<p>
Eat and enjoy! </p>
<p><strong>Update:</strong> <a href="http://blog.khymos.org/2007/04/09/carbonated-fruit-the-isi-way/">Carbonated fruit the iSi way!</a></p>
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