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	<title>Khymos &#187; meat</title>
	<atom:link href="http://blog.khymos.org/tag/meat/feed/" rel="self" type="application/rss+xml" />
	<link>http://blog.khymos.org</link>
	<description>- dedicated to molecular gastronomy</description>
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		<title>TFP 2011: Sous vide master class (part 2)</title>
		<link>http://blog.khymos.org/2011/04/01/tfp-2011-sous-vide-master-class-part-2/</link>
		<comments>http://blog.khymos.org/2011/04/01/tfp-2011-sous-vide-master-class-part-2/#comments</comments>
		<pubDate>Fri, 01 Apr 2011 22:36:09 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[equipment]]></category>
		<category><![CDATA[interview]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[science]]></category>
		<category><![CDATA[sous vide]]></category>
		<category><![CDATA[Bruno Goussault]]></category>
		<category><![CDATA[fish]]></category>
		<category><![CDATA[jus]]></category>
		<category><![CDATA[meat]]></category>
		<category><![CDATA[meat jus]]></category>
		<category><![CDATA[precise temperature]]></category>
		<category><![CDATA[right temperature]]></category>
		<category><![CDATA[Sang Hoon Degeimbre]]></category>
		<category><![CDATA[stepwise cooling]]></category>
		<category><![CDATA[stock]]></category>
		<category><![CDATA[Thomas Bühner]]></category>
		<category><![CDATA[vacuum chamber]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=2819</guid>
		<description><![CDATA[Sous vide fish should be cooked at several temperatures followed by stepwise cooling for the best texture Bruno Goussault started the sous vide master class at The Flemish Primitives 2011 by arguing that precise temperature or right temperature cooking is a better term than low temperature cooking. It&#8217;s really about knowing at which temperature the [...]]]></description>
			<content:encoded><![CDATA[<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-fish.jpg"><img class="alignnone size-full wp-image-2827" title="tfp2011-svmc-fish" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-fish.jpg" alt="" width="620" height="620" /></a><br />
<em>Sous vide fish should be cooked at several temperatures followed by stepwise cooling for the best texture</em></p>
<p>Bruno Goussault started the sous vide master class at <a title="The Flemish Primitives 2011 (part 1)" href="http://blog.khymos.org/2011/03/26/the-flemish-primitives-2011-part-1/">The Flemish Primitives 2011</a> by arguing that <strong>precise temperature or right temperature cooking is a better term than low temperature cooking</strong>. It&#8217;s really about knowing at which temperature the desired change takes place (or even better: knowing which time-temperature combinations will yield the desired results &#8211; this is a topic I will come back to soon).</p>
<p>Recounting the early days of sous vide, Bruno Goussault explained how he was once asked about how to produce prepare tender meat from a though cut. He was aware of a science paper on a slow cooking technique from USA (anyone know which paper this was?). It utilized a water bath, but the water washed away the juices. To avoid this Bruno wrapped the meat in cling film. A roast beef cooked at 58 °C turned out tender with a nice pink color. Then a friend working with plastics suggested that he should look into polyethylene (PE) bags in combination with a sous vide machine (boil-in-bag had already been around for some time apparently). Interestingly Bruno mentioned that during a recent Bocuse d&#8217;Or competition in USA where Bruno trained the American team, they replaced the plastic with a &#8220;skin&#8221; made from shrimps. Maybe we will see more &#8220;edible&#8221; skins used in sous vide in the future?</p>
<p>VACUUMING<br />
Bruno then went on to talk about the vacuuming process and how time/pressure profiles should be adjusted <span id="more-2819"></span>to <strong>respect the shape and properties of the product</strong>, in particular when working with fish. A challenge with vegetables is the enzymatic release of ethylene, causing the bags to inflate (resulting in a poor heat conduction). <strong>The advice for vegetables and potatoes: use maximuum vacuum.</strong> But if you use the same setting for poultry the bones will turn out black because you extract bone marrow through the bones. Thus the vacuum should be sufficient to extract air from the bones, but not so high that the marrow is extracted.</p>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-oyster.jpg"><img title="tfp2011-svmc-oyster" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-oyster.jpg" alt="" width="620" height="620" /></a><br />
<em>Vacuum packing turns out to be a great way to impregnate food with flavors. As an example Sang-Hoon Degeimbre prepared oysters impregnated with champagne,  cooked for 5 min at 83 °C and served with kiwi extract and an oyster leaf, Mertensia maritimia (Thanks Arielle!).</em></p>
<p>COLOR<br />
When working with vegetables it is always the <a href="http://en.wikipedia.org/wiki/Chlorophyll">chlorophyll</a> which causes problems (not the red/orange <a href="http://en.wikipedia.org/wiki/Carotene">carotenes</a> or the red/blue/purple <a href="http://en.wikipedia.org/wiki/Anthocyan">anthocyans</a>). This is due to the loss of the central magnesium ion. The easiest way to prevent this is by raising the pH. This can be done with baking soda (sodium bicarbonate), but gives an awful taste  according to Bruno (and personally I would add that bicarbonate easily  gives a mushy texture as well). A more advanced way to preserve the bright green color would be to add some other alkalizing/buffering agent such as <a href="http://en.wikipedia.org/wiki/Sodium_triphosphate">sodium triphosphate</a> (aka as sodium polyphosphate) or <a href="http://en.wikipedia.org/wiki/Sodium_hexametaphosphate">sodium hexametaphosphate</a> (if you&#8217;re really interested, check out the paper <a href="http://pdfcast.org/download/page-1-effect-of-ph-on-chlorophyll-degradation-and-colour-loss-in-blanched-green-peas.pdf">Effect of pH on chlorophyll degradation and colour loss in blanched green peas</a> for instance). And while we&#8217;re discussing color:  a side effect of the vacuum packaging of vegetables is that the air cells collaps, thereby reducing the diffraction of light which results in a darker and more intense green color.</p>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-SH.jpg"><img class="alignnone size-full wp-image-2828" title="tfp2011-svmc-SH" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-SH.jpg" alt="" width="620" height="620" /></a><br />
<em>Sang-Hoon Degeimbre shows how vacuuming gives greens a darker green color</em></p>
<p>STEPWISE COOLING<br />
In restaurants sous vide is often used in a cook-chill-reheat fashion. For such a setup Bruno argued that it is vital to <strong>cool the meat or fish stepwise to allow a readsorption of the exudated juices</strong> (which also dissolve/carry away spices and Maillard products on the surface). If plunged directly into ice water fat and gelatin can cause the juices to gel, thereby effectively preventing a readsorption of the liquid. By taking the temperature down in a more controlled way the water holding capacity of fish/meat is improved and a portion of the exudated juice will be readsorbed (together with the flavors from the surface). A suggested stepwise cooling protocol for fish could be as follows: 10 min at room temperature, 10 min in cold water followed by 2 h in ice water. And it&#8217;s even possible to elaborate further on this &#8211; Bruno mentioned that he had developed a 4 step SV procedure followed by a 3 step chilling for Joel Robuchon. To me this also suggests that meat which is inteded for immediate serving should also rest a couple of minutes in the presence of the exudated juices. Would be interesting to know more about which factors influence this readsorption actually (maybe an interesting topic of a masters/PhD project?).</p>
<p>FISH<br />
When preparing fish it is recommended to allow the fish to soak in a 5% brine for 10 min (Bruno lived for 3 years in Stavanger in Norway, and learnt this from a Norwegian chef during his stay &#8211; unfortunately he could not remember his name). This increases the osmotic pressure in the cells and <strong>prevents albumin from escaping</strong> (think of baked salmon with lot&#8217;s of white albumin leaking out) according to Bruno. After brining the recommended cooking times for a fish filet is then 1-3 min at 83 °C for pasteurization followed by 5 min at 58 °C for finishing.</p>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-3wb.jpg"><img title="tfp2011-svmc-3wb" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-3wb.jpg" alt="" width="620" height="173" /></a><br />
<em>Water baths set at 58, 66 and 83 °C. For a restaurant with only three water baths these are the recommended compromise temperatures.</em></p>
<p>TEMPERATURE<br />
The many recommended temperature settings for meats and fish can be a challenge in a restaurant setting with a limited number of water baths. Bruno&#8217;s simplified approach was therefore to have three water baths at the following temperatures:</p>
<ul>
<li><strong>58 °C</strong> (and in any case below 62 °C): At 56 °C albumin is sill runny, at 58 °C it begins to whiten (and the overall color of meat is actually a result of seeing the red meat color through a white &#8220;fog&#8221; of albumin covering the muscle fibres. This temperature is recommended for <strong>fish and meat that is to be served red</strong>.</li>
<li><strong>66 °C</strong> (in any case below 68 °C): The water holding capacity of the muscle tissue is dramatically reduced when heated above 68 °C. A temperature of 66 °C is therefore appropriate to retain the juiciness of meat. This temperature is recommended for <strong>poultry and well done meat</strong>.</li>
<li><strong>83 °C</strong> (in any case below 85 °C): This temperature is <strong>suitable for vegetables</strong> as they need a temperature above 80 °C to be properly cooked, but at 85 °C pectin begins to hydrolyze so it&#8217;s important to stay below that temperature. This temperature is also suitable for a <strong>quick pasteurization of the surface of fish and meat</strong>.</li>
</ul>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-potatoe.jpg"><img title="tfp2011-svmc-potatoe" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-potatoe.jpg" alt="" width="620" height="620" /></a><br />
<em>Potatoes cooked for 3.5 h at 83 °C turn out really delicious.</em></p>
<p>HYDROLYSIS OF CONNECTIVE TISSUE<br />
The hydrolysis of connective tissue was also briefly mentioned. For a though cut of meat such as shoulder or top blade 4 h at 100 °C are needed to break down the connective tissue. <strong>At 66 °C the same process takes 76 h, and further lowering the temperature to 56 °C will require a full 120 h for the similar break down of the connective tissue.</strong> But in return the low temperature gives a meat with a very nice color. Interestingly, Bruno mentioned that due to different aging practices a similar cut in the USA typically would only require 72h at 56 °C to reach the same tenderness! So the time/temperature combinations should only be used as rough guides.</p>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-lamb.jpg"><img class="alignnone size-full wp-image-2824" title="tfp2011-svmc-lamb" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-lamb.jpg" alt="" width="620" height="620" /></a><br />
<em>Lamb cooked for 36h at 66 °C has a very nice texture!</em></p>
<p>Other tips &amp; tricks:</p>
<ul>
<li>Rabbit and game are difficult to cook sous vide: sugar/glycogen in the muscles is converted into lactic acid which inhibits the cooking process (does anyone have more background information on this?)</li>
<li>The <a href="http://www.wolframalpha.com/input/?i=boiling+point+of+water+at+10+mbar">boling point of water at 10 mbar is 6.9 °C</a>. This is the reason why everything you plan to vacuum pack at this temperature should be cooled to below 6 °C, otherwise the liquid will start to boil in the vacuum.</li>
<li> Regardless of what is cooked Bruno recommended a quick dip into a 83 °C water bath for pasteurization.</li>
<li>It is better to generate Maillard flavors before sous vide cooking: the flavors will dissolve in the exudated meat juices and then be readsorbed by applying a proper stepwise cooling. If desired a short browning can be applied after sous vide cooking for crisping of the surface.</li>
</ul>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-BG.jpg"><img class="alignnone size-full wp-image-2820" title="tfp2011-svmc-BG" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-BG.jpg" alt="" width="620" height="620" /></a><br />
<em>A very engaged Bruno sharing his knowledge about sous vide cooking</em></p>
<p>At the end of the session I got to chat a little with Bruno. He said that he was very happy about the wide spread use of sous vide, but also emphasized that it is a technique that can <strong>amplify mistakes as well as successes</strong>. -Many chefs don&#8217;t respect the temperature recommendations! I<strong> visited a chef who cooked meat at 54 °C and it smelled terrible</strong>, Bruno told me. The different bacterias can greatly influence the flavor of the resulting product if care is not taken to eliminate them. I asked Bruno about low temperature/long time combinations, but he said that chefs generally are not patient enough. They already complain that they don&#8217;t have time for the long sous vide preparations. Bruno does a lot of sous vide consulting for chefs and restaurants (in France/Europe through <a href="http://www.lecrea.com/presentation.php">CREA</a> founded by him in 1991 and in the US as a consultant for <a href="http://www.lecrea.com/presentation.php">Cuisine solutions</a>), but does not have big hopes for sous vide in home cooking: <strong>- No, it&#8217;s a gadget! Sous vide works best for cook &amp; chill in a restaurant setting.</strong></p>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-TB.jpg"><img class="alignnone size-full wp-image-2826" title="tfp2011-svmc-TB" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-TB.jpg" alt="" width="620" height="620" /></a><br />
<em>Thomas Bühner explaining how his &#8220;raw&#8221; meat jus is prepared. In the background the minced meat is being prepared.</em></p>
<p>(RAW) MEAT JUS<br />
In the last part of the master class the German chef Thomas Bühner (<a href="http://www.restaurant-lavie.de/">La Vie</a>, Osnabrück) demonstrated the preparation of meat jus (i.e. the natural juice given of by meat when heated). Ground meat was vacuumed and cooked for 2.5 h at 56 °C. The meat juice was then collected using a chinois and further concentrated using a rotary evaporator operated at 120 mbar and a water bath temperature of 40-50 °C (important to keep the water below the temperature of the sous vide water bath in order to retain the raw meat flavor). Compared to a conventional cleared stock the reddish meat jus is opaque. <strong>The meat jus is devoid of Maillard flavors</strong> due to the low temperature used, and this ensures a raw and bloody taste. The taste was interesting I would say, but perhaps not very delicious on it&#8217;s own &#8230; But I&#8217;m curious how it&#8217;s actually incorporated in his restaurant.</p>
<p><a href="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-jus.jpg"><img class="alignnone size-full wp-image-2825" title="tfp2011-svmc-jus" src="http://blog.khymos.org/wp-content/2011/03/tfp2011-svmc-jus.jpg" alt="" width="620" height="620" /></a><br />
<em>Conventional stock (left) and evaporated meat jus (right)</em></p>
<p>Thomas Bühner also demonstrated vacuum infusion using the Gastrovac. Potatoes were pierced/scorched, submerged in the truffle jus and then placed in the vacuum of the gastrovac. Thomas then repeatedly let air into the Gastrovac to allow cells to collapse and improve the impregnation.</p>
<img src="http://blog.khymos.org/?ak_action=api_record_view&id=2819&type=feed" alt="" />]]></content:encoded>
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		<slash:comments>23</slash:comments>
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		<item>
		<title>A pinch of salt for your coffee, Sir?</title>
		<link>http://blog.khymos.org/2010/03/21/a-pinch-of-salt-for-your-coffee-sir/</link>
		<comments>http://blog.khymos.org/2010/03/21/a-pinch-of-salt-for-your-coffee-sir/#comments</comments>
		<pubDate>Sun, 21 Mar 2010 22:33:24 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[science]]></category>
		<category><![CDATA[tips & tricks]]></category>
		<category><![CDATA[bitter]]></category>
		<category><![CDATA[bitterness]]></category>
		<category><![CDATA[coffee]]></category>
		<category><![CDATA[cured ham]]></category>
		<category><![CDATA[meat]]></category>
		<category><![CDATA[salt]]></category>
		<category><![CDATA[taste suppression]]></category>
		<category><![CDATA[tonic water]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=2182</guid>
		<description><![CDATA[A small sprinkle of salt will suppress bitterness &#8211; and in some cases it can benefit the overall coffee flavor. I&#8217;ve tried it with an espresso and somehow it works, but it&#8217;s difficult to describe the flavor. I prefer my coffee black, and politely decline when offered milk and sugar. However, if offered salt I [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2010/03/espress-with-salt.jpg" alt="" title="espress-with-salt" width="620" height="620" class="alignnone size-full wp-image-2187" /><br />
<em>A small sprinkle of salt will suppress bitterness &#8211; and in some cases it can benefit the overall coffee flavor. I&#8217;ve tried it with an espresso and somehow it works, but it&#8217;s difficult to describe the flavor.</em></p>
<p>I prefer my coffee black, and politely decline when offered milk and sugar. However, if offered salt I would probably smile and say &#8220;Yes, please!&#8221; Salt???! It turns out that <strong>adding salt to coffee is not as weird as it may sound at first</strong>. There is a tradition for adding a pinch of salt to coffee in Northern Scandinavia, Sibir, Turkey and Hungary. And when available, such as in coastal areas where fresh water from rivers mixes with the salt sea, one would simply use <a href="http://en.wikipedia.org/wiki/Brackish_water">brackish water</a> when preparing coffee. This water typically has a salt content of 0.5-3%, which is lower than the average 3.5% in seawater. This results in a more intense taste and more foaming. And if living far from the sea, the <a href="http://matalskaren.taffel.se/">Swedish food blogger</a> Lisa Förare Winbladh let me know that in Northern Sweden one would deliberately add salt if using melt water from glaciers for making coffee. But tradition aside, is there a scientific explanation of this widespread tradition of preparing coffee with addition of salt?<br />
<span id="more-2182"></span></p>
<p>The first thing that comes to mind is that salt reduces bitterness. And to be more precise it is the sodium ion (Na<sup>+</sup>) that interferes with the transduction mechanism of bitter taste. But interestingly the mechanism behind this is not fully understood! One of my <a href="http://blog.khymos.org/2006/10/01/suppresion-of-bitterness/">very first blog posts</a> was about tonic water and how one by adding salt can suppress the bitter taste and make tonic water more or less sweet. It&#8217;s a fascinating experiment that you should try at home. Expect to use about 1,5-2 g salt for a glass with roughly 1,5 dL (150 g) of tonic water. It&#8217;s a good idea to start with a little salt and taste it as you go.</p>
<p><img src="http://blog.khymos.org/wp-content/2010/03/tonic_water_closeup.jpg" alt="" title="tonic_water_closeup" width="620" height="620" class="alignnone size-full wp-image-2183" /><br />
<em>Try adding a little salt to tonic water &#8211; the effect is quite surprising: The characteristic bitterness from the added <a href="http://en.wikipedia.org/wiki/Quinine">quinine</a> disappears!</em></p>
<p>Bitterness is an important flavor in coffee, but under less-than-optimal extraction conditions it can be too dominant. Generally bitter tasting compounds are less water soluble than other coffee flavors, hence the bitter compounds are extracted towards the end of the brewing. High temperatures (close to boiling) and long extraction times also favor bitterness. In that respect the <a href="http://en.wikipedia.org/wiki/Coffee_percolator">coffee percolator</a> is known to produce rather bitter, over-extracted coffee due to near boiling temperatures, and such coffee would most likely benefit from a little salt! And before the percolator came the ground coffee was just put into the boiling water and then left to settle. I can really imagine how brackish water could actually benefit</p>
<p>But the salt need not be reserved for over-extracted coffee. I&#8217;ve tried using salt both in a drip coffee maker and in the filter basked when pulling an espresso. The tests were very un-scientific, but the tiny amount of salt does <strong>dampen bitterness and change the coffee taste</strong> (but the coffee does not have a salty taste). Since I lack cupping experience, I certainly lack the language to describe how salt influences the taste, so I leave it up to you to try it out! And maybe some baristas with cupping experience can fill me out on this and do some tests? </p>
<p>In stead of just using plain salt with coffee, <em>cured ham would signal rafinesse</em> if served in central Europe, whereas in Northern Sweden there is a tradition for serving dried meat with coffee. The Swedish author <A HREF="http://en.wikipedia.org/wiki/Mikael_Niemi">Mikael Niemi</A> describes this in his novel <A HREF="http://www.amazon.com/exec/obidos/ASIN/1583226591/kjemiihverdao-20">Popular music from Vittula</A>:</p>
<blockquote><p>&#8220;&#8230; and then the <I>pièce de résistance</I> among all the sweetmeats: a hard, brown lump of dried reindeer meat. Salty slices were cut and placed in the coffee, chunks of coffee-cheese stirred in, and white sugar lumps were held between the lips. And then, fingers trembling, we all poured the coffee mixture into our saucers, and slurped our way to heaven.&#8221;</p></blockquote>
<p>With cured ham, apart from the salt-coffee interaction, one also has the combination of meat and coffee. From previous flavor pairing rounds <a href="http://blog.khymos.org/tgrwt/">TGRWT</a> #1 and #5 (chocolate/coffee and coffee/meat respectively) we have seen that coffee and meat in some ways approach each other and are actually a good combination. A secret tip BTW is to add a little coffee to your beef stocks for extra depth and richness &#8211; this works because coffee shares many impact flavors with browned meats due to the Maillard reaction.</p>
<p><strong>Now I&#8217;m curious &#8211; are you aware of coffee-salt combinations in your own country? Please tell me about it! And if you try a pinch of salt in your coffee &#8211; how did it taste?</strong></p>
<p><strong>Update</strong>: Read about my <a href="http://blog.khymos.org/2010/03/31/testing-salt-in-coffee-with-tim-wendelboe/">tests of coffee with salt at Tim Wendelboe&#8217;s coffe shop</a></p>
<p>&#8211;<br />
Some articles that discuss the role of sodium ions (Na<sup>+</sup>) in suppression of bitter receptors:</p>
<p>Breslin, P. A. S; Beauchamp, G.K. <a href="http://chemse.oxfordjournals.org/cgi/content/abstract/20/6/609">&#8220;Suppression of Bitterness by Sodium: Variation Among Bitter Taste Stimuli&#8221;</a> <em>Chemical Senses</em> <strong>1995</strong>, 20, 609-623.</p>
<p>Breslin, P. A. S; Beauchamp, G.K. <a href="http://dx.doi.org/10.1038/42388">&#8220;Salt enhances flavour by suppressing bitterness&#8221;</a> <em>Nature</em> <strong>1997</strong> (387), 563.</p>
<p>Bresling, P. A. S <a href="http://dx.doi.org/10.1016/S0924-2244(96)10039-X">&#8220;Interactions among salty, sour and bitter compounds&#8221;</a> <em>Trends in Food Science &#038; Technology</em> <strong>1996</strong> (7), 390. (<a href="http://duffylab.ah.uconn.edu/pubs/misc/breslin1996-tfst-flavor.pdf">free download</a>)</p>
<p>Keast, R. S. J.; Breslin, P. A. S. <a href="http://dx.doi.org/10.1016/S0950-3293(02)00110-6">&#8220;An overview of binary taste–taste interactions&#8221;</a> <em>Food Quality and Preference</em> <strong>2003</strong>, 14(2), 111.</p>
<p>In addition to suppression of bitterness, salt can enhance sweetness at low concentrations and umami flavors at higher concentrations (more about this in <a href="http://blog.khymos.org/2007/05/01/practical-molecular-gastronomy-part-5/">part 5</a> of <a href="http://blog.khymos.org/tag/10-tips/">&#8220;Practical tips for molecular gastronomy&#8221;</a>).</p>
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		<slash:comments>60</slash:comments>
		</item>
		<item>
		<title>The science of BBQ</title>
		<link>http://blog.khymos.org/2008/04/04/the-science-of-bbq/</link>
		<comments>http://blog.khymos.org/2008/04/04/the-science-of-bbq/#comments</comments>
		<pubDate>Fri, 04 Apr 2008 13:30:03 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[bbq]]></category>
		<category><![CDATA[brine]]></category>
		<category><![CDATA[dry rub]]></category>
		<category><![CDATA[FAB]]></category>
		<category><![CDATA[grill]]></category>
		<category><![CDATA[Harold McGee]]></category>
		<category><![CDATA[Heston Blumenthal]]></category>
		<category><![CDATA[maillard]]></category>
		<category><![CDATA[Maillard reaction]]></category>
		<category><![CDATA[marinade]]></category>
		<category><![CDATA[marinate]]></category>
		<category><![CDATA[meat]]></category>
		<category><![CDATA[sealing]]></category>
		<category><![CDATA[searing]]></category>
		<category><![CDATA[smoke ring]]></category>
		<category><![CDATA[temperature]]></category>
		<category><![CDATA[umami]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2008/04/04/the-science-of-bbq/</guid>
		<description><![CDATA[Photo by spielzimmer via flickr.com (CC). Eric Devlin over at Home of BBQ interviewed me via email about BBQ and molecular gastronomy. The topic should be of interest to the readers of Khymos as well, so I post the questions and answers in extenso here for your benefit. Q. Martin, thank you for taking the [...]]]></description>
			<content:encoded><![CDATA[<p><img src='http://blog.khymos.org/wp-content/2008/04/bbq-hot-air.jpg' alt='bbq-hot-air.jpg' /><br />
<em><a href="http://flickr.com/photos/spielzimmer/521260074/">Photo</a> by <a href="http://flickr.com/photos/spielzimmer/">spielzimmer</a> via flickr.com (<a href="http://creativecommons.org/licenses/by/2.0/">CC</a>). </em></p>
<p>Eric Devlin over at <a href="http://www.homeofbbq.com/">Home of BBQ</a> interviewed me via email about <a href="http://www.homeofbbq.com/2008/04/interview-martin-lersch-of-khymos.html">BBQ and molecular gastronomy</a>. The topic should be of interest to the readers of Khymos as well, so I post the questions and answers <em>in extenso</em> here for your benefit.</p>
<blockquote><p><strong>Q. Martin, thank you for taking the time to discuss the science of BBQ. Before we get into ‘low and slow’ cooking, can you tell us a bit about your background and your interest in food?</strong><br />
mail<br />
I have a PhD in chemistry and currently I&#8217;m working as a research scientist. When I first became interested in the connection between food and chemistry in the late 90&#8242;s, I searched the Internet without finding much information. I did however find some very interesting books in the faculty library, including Harold McGee&#8217;s &#8220;On Food and Cooking &#8211; The Science and Lore of the Kitchen&#8221;. Having found books about the subject, I soon started to give popular science presentations. In 2004 I was invited to attend the &#8220;International Workshop on Molecular Gastronomy&#8221; in Erice, Sicily. This was a great experience and I enjoyed meeting many of the scientists, writers and chefs involved with molecular gastronomy. The website I&#8217;ve put up, Khymos, is in many ways what I would have liked to find at the time I became interested in the subject.</p>
<p><strong>Q. Over the past few years we have been hearing quite a bit about how food cooked over a hot flame can have increased carcinogens. Would food that is cooked for a longer period of time over a lower heat be safer?<br />
</strong><br />
The carcinogens are formed when meat gets burnt, so although you&#8217;d like to use high heat to get the Maillard reaction going (which gives you both flavor and color) you don&#8217;t want to overdo it. But even if the meat gets a little burnt, it is a good thing that for the carcinogens, as for all other substances, the poison is in the dose. So if you eat grilled meat every day you should be concerned about this, but for most people I think overeating poses a much greater risk!</p>
<p><strong>Q. Serious BBQ cooks like to produce a ‘bark’ when preparing pork for their pulled pork dishes. Usually the natural ‘bark’ of the meat is enhanced by the sugar found in the dry rubs that are applied. Is there any other method that could be used to achieve or increase those results? Maybe an egg wash prior to cooking?</strong></p>
<p>There are several processes which contribute to the flavor formation. First you have the sugars which caramelize. As you correctly state, this is enhanced by adding sugar to the rubs. Furthermore you have the Maillard reaction were sugars react with amino acids to form a host of compounds which contribute both flavor and color. Even though the Maillard reaction can take place at low temperature (such as in vintage champagne), things really speed up when temperature rises above 110-120 °C. Obviously to reach this temperature you&#8217;ll have to get rid of the water first. So using a dry rub makes sense. Apart from that it&#8217;s mostly about being patient. Use fresh spices, and where possible whole spices that you ground prior to use. The heat of the grill will toast the spices, thereby intensifying the flavor even more.</p>
<p>I must admit that I have never made nor tasted meat which was prepared with a &#8220;bark&#8221;, so I don&#8217;t dare to go into further details concerning how to improve it. The best thing would be to cook two pieces of meat in parallel, for instance with and without an egg wash to see which one comes out best.</p>
<p><strong>Q. BBQ sauces vary greatly depending on region. Carolina sauces are often thin, while Kansas City and Texas sauces have greater viscosity. If a cook is making a sauce that comes out too thin, what recommendations would you have to thicken it?</strong></p>
<p>You either have to take out some of the water by letting it boil over low heat in a large, wide pot, or you can add a thickening agent such as corn starch. If you use onions, these will help thicken your sauce if you let it boil for a while.</p>
<p><strong>Q. In competitions, some BBQ pit-masters utilize a flavor enhancer called FAB B, which contains msg. The thought behind this additive is that after a judge has consumed numerous samples of the same category of meat, the additive will stimulate the taste buds and help to separate that entry from the rest. Can you recommend any other method of ‘waking the taste buds’ without detracting from the taste?</strong></p>
<p>The problem with this explanation is that if everyone uses FAB, will there be any effect at all? If the idea is to rinse the mouth you would want something acidic which stimulates saliva production, some tannic compounds to bind proteins and perhaps some alcohol to help solubilize fats. Heston Blumentahl at the Fat Duck made a <a href="http://www.rsc.org/chemistryworld/Issues/2005/May/Cookedtoperfection.asp">&#8220;Green tea sour mousse&#8221;</a> from these guidelines.</p>
<p>But even so adaption and habituation occurs in all tasting. I&#8217;ve discussed this extensively in a <a href="http://blog.khymos.org/2007/07/01/ten-tips-for-practical-molecular-gastronomy-part-6/">blog post</a>, and the easy answer is variation. Or more scientifically: increased sensing by contrast amplification. Eat something which is as far from meat as you can come, something which is cold, crisp, fresh and acidic (did someone mention a tasty salad?). This will make the next piece of meat taste much better!</p>
<p><strong>Q. FAB contains the following: Hydrolyzed soy protein, vegetable oil (soybean and or corn, cottonseed), sodium phosphates, mono sodium glutamate, autolyzed yeast extract, disodium inosinate and guanylate, xanthan gum. They claim that it enhances natural meat flavors, makes your BBQ juicier, improves texture for better slicing and taste and increases yields. Would you believe that these claims are accurate? Would you recommend other methods to achieve the same results?<br />
</strong></p>
<p>I would like to emphasize that MSG&#8217;s bad reputation is somewhat undeserved. MSG is the salt of a naturally occurring amino acids and is found in many foods. Parmesan and tomatoes contain lots of it (ever wondered why the Italians sprinkle so much parmesan on their food?). Protein and yeast are excellent sources for MSG and the related compounds listed, so I absolutely believe the claim that FAB will enhance the meaty flavors. When FAB is used in a marinade, the phosphates enhance juiciness and improve texture (more on this later). This is well documented. But even so, every chef should remember that FAB or other products can only make good meat better. Therefore you should pay close attention to the quality of the meat you use.</p>
<p><strong>Q. What is a smoke ring and how is it created? What is the best method of producing a significant smoke ring?<br />
</strong><br />
When wood or coal burns, small amounts of nitrogen dioxide is formed which dissolves in the surface of the meat, thereby creating nitrous acid. The acid diffuses further into the meat, and when converted to nitric oxide it reacts with myoglobin to form a stable pink colored molecule.</p>
<p><strong>Q. Is there a point of delineating returns, where a piece of meat will no longer absorb the flavor of the wood that it is cooked with? Are you wasting your time by adding more wood for flavor after a certain point?</strong></p>
<p>Frankly, I don&#8217;t know. I think this question should be answered by a chef!</p>
<p><strong>Q. How effective is brining and marinating such as pork shoulder or brisket? How much penetration can you reasonably expect? As competitors often work with a short time frame, is there a way to speed up the results of a marinade? And if alcohol burns off, what&#8217;s the advantage of using wine instead of juice? Does the alcohol &#8220;do&#8221; something before it burns off?</strong></p>
<p>Marinades penetrate meat very slowly, so it should primarily be regarded as a way of adding taste to the surface of the meat (which it does very well). An exception here is chicken and fish which are more easily penetrated by marinades. To speed up marination, use water based, concentrated marinades and leave the meat at room temperature. Piercing the meat with a jaccard will allow the marinade to work from the &#8220;inside&#8221; as well.</p>
<p>It is perfectly fine to use wine in a marinade. The alcohol will dissolve some fat which can speed up penetration. Wine also contains organic acids which can have a tenderizing effect. Phenolic compounds (tannins) will react with meat proteins to form insoluble complexes which in turn makes meat more juicy and tender (even though the exact reason for this is not understood). Experiments have shown that red wine works better than white in marinades.</p>
<p>An interesting thing with marinades is that to maximize the water retaining capacity of beef, your marinade should not contain both acids and salt as this will in fact lower the water holding capacity! If you go for acids, you can easily add salt later on.</p>
<p>Brining, which is immersing meat in water with about 5% salt, does make sense as the salt helps untangle protein strands. This allows spices to penetrate the meat more easily, and it renders meat juicier. Furthermore it lowers the temperature at which the proteins become &#8220;cooked&#8221;.</p>
<p><strong>Q. Would searing a piece of meat help to ‘seal’ the juices and allow for a more moist cut?</strong></p>
<p>No. As Harold McGee pointed out, &#8220;searing is not sealing&#8221;. The only reason to sear meat is to get the Maillard reaction going.</p>
<p><strong>Q. What recommendations would you give to someone that is cooking over wood in a smoker if they wanted to achieve a crisp skin on chicken?</strong></p>
<p>In a smoker the low heat will only be enough to evaporate the water, but only very slowly turn the tough collagen into tender gelatin. To achieve this you&#8217;ll need a higher temperature, preferably temperatures around 80-90 °C. But even in a smoker there are a couple of things you can do to improve the crispiness. Use a chicken which has been dry-processed. Alternatively, let the chicken dry uncovered in the fridge for a day. Oiling the skin will improve the heat transfer. You can also pierce the skin to let the juices evaporate.</p>
<p><strong>Q. Barbecuing is often seen as the art of taking a piece of meat that is tough and/or stringy and producing a tender, mouthwatering meal from it. What is it that occurs that renders a tough cut like brisket into a soft, enjoyable meat? Is there anything that can be done to enhance those efforts?</strong></p>
<p>The muscle fibers themselves are tender, but they are held together by connective tissue of which collagen is most abundant. Collagen is tough, but when heated it slowly dissolves and forms gelatin which is very tender. Collagen in young animals dissolves more easily than that of older animals. Collagen starts do dissolve around 70 °C and at 90 °C it dissolves rapidly. But before the temperature get this high enzymes which are present in the meat will help tenderize it. These enzymes lose their activity between 40 and 50 °C, but when you barbecue at low heat the meat will spend quite some time below 40-50 °C.</p>
<p><strong>Q. Why do some meats, after reaching optimal tenderness, seem to get even more tender the longer you cook, while others tend to get tougher if you cook past ideal time?</strong></p>
<p>Preparing meat is more about temperature than time. If you like your beef medium rare you would aim for the center to be 55 °C. Continued heating will cause more proteins to denature and as the contract, water is expelled leaving the dry and rubbery. Unless you have prepared your meat at a temperature very close to the desired temperature of the center, there will be a temperature gradient. So even if you remove the meat from your heating source when the center reaches the desired temperature, the warmer outside of the meat will continue to cook the center as it rests, bringing it outside your desired temperature range. It takes experience to know exactly when to remove the meat from the heat.</p>
<p><strong>Q. What&#8217;s happening to the meat during &#8220;resting&#8221;? Why is this recommended prior to cutting and serving?</strong></p>
<p>Apart from the leveling out of the temperature gradient discussed in the previous question it is a very good idea let meat rest before serving, as this improves the water holding capacity of the meat. This in turn reduces the amount of juice you loose when you carve or slice the meat.</p></blockquote>
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		<title>TGRWT #5: Grilled pork tenderloin with chocholate beef stock cream</title>
		<link>http://blog.khymos.org/2007/08/26/tgrwt-5-grilled-pork-tenderloin-with-chocholate-beef-stock-cream/</link>
		<comments>http://blog.khymos.org/2007/08/26/tgrwt-5-grilled-pork-tenderloin-with-chocholate-beef-stock-cream/#comments</comments>
		<pubDate>Sun, 26 Aug 2007 22:27:12 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[hydrocolloids]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[tips & tricks]]></category>
		<category><![CDATA[chocolate]]></category>
		<category><![CDATA[Ferran Adria]]></category>
		<category><![CDATA[grilling]]></category>
		<category><![CDATA[meat]]></category>
		<category><![CDATA[pork]]></category>
		<category><![CDATA[stock]]></category>
		<category><![CDATA[techniques]]></category>
		<category><![CDATA[texture]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/08/26/tgrwt-5-grilled-pork-tenderloin-with-chocholate-beef-stock-cream/</guid>
		<description><![CDATA[This month&#8217;s TGRWT is hosted by Le Petite Boulanger, and the foods to pair are chocolate and meat. The recipe for the chocolate beef stock cream is inspired by the Iberian Ham Cream by Ferran Adrià/El Bulli (the recipe can be found on p. 21 in the hydrocolloid recipe collection). I used anis because it [...]]]></description>
			<content:encoded><![CDATA[<p><img src='http://blog.khymos.org/wp-content/2007/08/chocolate-beef-stock-cream.jpg' alt='chocolate-beef-stock-cream.jpg' /></p>
<p>This month&#8217;s <a href="http://lepetiteboulanger.blogspot.com/2007/08/announcement-chocolate-and-meat-tgrwt-5.html">TGRWT</a> is hosted by Le Petite Boulanger, and the foods to pair are chocolate and meat. The recipe for the chocolate beef stock cream is inspired by the Iberian Ham Cream by Ferran Adrià/El Bulli (the recipe can be found on p. 21 in the <a href="http://blog.khymos.org/2007/08/14/hydrocolloid-recipe-collection/">hydrocolloid recipe collection</a>). I used anis because it brings out the meatiness very well. After mixing in the olive oil I saw that the droplets were not properly dispersed. Addition of some lecithin which solved this problem. </p>
<p><strong>Chocolate beef stock cream</strong><br />
100 g water<br />
2 g beef stock powder<br />
10 g chocolate (70%)<br />
1/4 t anis, powdered<br />
0.5 g xanthan<br />
0.2 g lecithin<br />
20 g olive oil<br />
honey and chili oil to taste</p>
<p>Heat water to dilute beef stock and melt chocolate. Cool. Add xanthan and lecithin. Mix with immersion blender. Add olive oil. Mix until smooth texture. Sprinkle with chives.</p>
<p><strong>Grilled pork tenderloin</strong><br />
pork tenderloin, cut in 3 cm thick pieces<br />
oil<br />
powdered anis<br />
crushed garlic</p>
<p>Marinate meat with oil, garlic and anis mixture. Grill. Serve together with the chocolate meat broth cream.</p>
<p><img src='http://blog.khymos.org/wp-content/2007/08/pork-chocolate-beef-stock-cream.jpg' alt='pork-chocolate-beef-stock-cream.jpg' /></p>
<p>Verdict: The chocolate beef stock cream has very meaty and almost nutty flavour. Honey is important to round of the otherwise slightly bitter taste of the chocolate. Chili oil gives it a bite, but can be omitted. </p>
<p>You can get an impression of the texture from this video:</p>
<p><object width="425" height="350"><param name="movie" value="http://www.youtube.com/v/0qNbJuFCvD4"></param> <embed src="http://www.youtube.com/v/0qNbJuFCvD4" type="application/x-shockwave-flash" width="425" height="350"></embed></object></p>
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		<title>Perfect steak with DIY &#8220;sous vide&#8221; cooking</title>
		<link>http://blog.khymos.org/2007/01/21/perfect-steak-with-diy-sous-vide-cooking/</link>
		<comments>http://blog.khymos.org/2007/01/21/perfect-steak-with-diy-sous-vide-cooking/#comments</comments>
		<pubDate>Sun, 21 Jan 2007 12:20:03 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[equipment]]></category>
		<category><![CDATA[experiments]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[science]]></category>
		<category><![CDATA[sous vide]]></category>
		<category><![CDATA[tips & tricks]]></category>
		<category><![CDATA[DIY]]></category>
		<category><![CDATA[do-it-yourself]]></category>
		<category><![CDATA[easy cooking]]></category>
		<category><![CDATA[heat capacity]]></category>
		<category><![CDATA[kitchen physics]]></category>
		<category><![CDATA[meat]]></category>
		<category><![CDATA[plastic bag]]></category>
		<category><![CDATA[temperature]]></category>
		<category><![CDATA[thermometer]]></category>
		<category><![CDATA[tools]]></category>
		<category><![CDATA[water]]></category>
		<category><![CDATA[water bath]]></category>
		<category><![CDATA[zip lock]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/01/21/perfect-steak-with-diy-sous-vide-cooking/</guid>
		<description><![CDATA[One important aspect of molecular gastronomy is the application of scientific principles to food preparation in a normal kitchen. This can very well be illustrated by discussing the preparation of a steak. The surface of the meat needs to be heated to > 120 °C (250 F) for the Maillard reaction to take place at [...]]]></description>
			<content:encoded><![CDATA[<p>One important aspect of molecular gastronomy is the application of scientific principles to food preparation in a normal kitchen. This can very well be illustrated by discussing the preparation of a steak. The surface of the meat needs to be heated to > 120 °C (250 F) for the <a href="http://www.exploratorium.edu/cooking/meat/INT-what-makes-flavor.html">Maillard reaction</a> to take place at a reasonable rate. This gives meat much of it&#8217;s characteristic aroma. The interior of the meat however should not be heated to more than 50-65 °C (120-150 F) for a rare or a medium rare appearance. If the heat is provided by a frying pan with a temperature typically in the range 120-160 °C (250-320 F), the different temperature required for the interior and the surface of the meat can actually be quite difficult to achieve. Bringing the meat to room temperature before cooking by taking it out of the fridge 1-2 hours in advance helps. Also, half way through the cooking it&#8217;s advisable to let the meat rest on a plate to allow the heat to diffuse into the interior and to let the surface cool down a little.</p>
<p>There is however an easier way to make a perfect steak! In restaurants the method has been around since the 70&#8242;s and is known under the name <a href="http://en.wikipedia.org/wiki/Sous_vide"><em>sous vide</em></a> (fr. under vacuum, more info on <a href="http://www.nytimes.com/2005/08/14/magazine/14CRYOVAC.html?pagewanted=1&#038;ei=5090&#038;en=3d5db17005368139&#038;ex=1281672000&#038;partner=rssuserland&#038;emc=rss">history of sous vide in this NY Times article</a>). The meat is packed in plastic bags, vacuumed and put into thermostated water baths. This equipment is not (yet?) found in the average kitchen. <strong>So here is a simple DIY procedure. You just use a normal plastic bag, leave the meat in the water bath for 30 min (or longer) and then quickly fry both sides to generate the products of the Maillard reaction.</strong> You do need a thermometer though to control the temperature of the water bath, preferably one with a dip in probe.</p>
<p>1. Put the meat (I used a <a href="http://en.wikipedia.org/wiki/Rib_eye_steak">rib eye steak</a> for this experiment) in a thick plastic bag. Only put one or two pieces of meat in each plastic bag &#8211; this ensures a greater contact surface with the water.</p>
<p><img id="image86" src="http://blog.khymos.org/wp-content/2007/01/meat-plastic-bag-1.jpg" alt="meat in plastic bag" /></p>
<p>2. Add any spices you like (salt and pepper always works well &#8211; for the experiment shown I used curry paste, soy sauce and chili sauce in stead), press (or suck) out the air and close the plastic bag tightly by tying a knot (or use a zip-lock bag). You don&#8217;t want any water to enter the bag!</p>
<p><img id="image87" src="http://blog.khymos.org/wp-content/2007/01/meat-plastic-bag-2.jpg" alt="meat in plastic bag" /></p>
<p>3. Heat a pot of water to the desired temperature (or use hot tap water) and place the plastic bag with meat in the water. Cover with a lid (not shown in the picture) to reduce heat loss. If you use a large pot of water it&#8217;s easier to keep the temperature constant. Also, it&#8217;s easier to control the temperature with an induction or gas stove top than with an electric plate since there is no additional heating once you turn them off. Regarding the temperature, start with 60 °C (140 F) and experiment from there (or check this <a href="http://en.wikipedia.org/wiki/Temperature_(meat)">table</a> at Wikipedia for doneness temperatures of meat). You should leave the meat in the water for at least 30 minutes &#8211; more for a thicker cut. But the good thing is you can leave it for much longer (several hours) provided the temperature does not come above 60 °C (or whatever temperature you decided on). A convenient way to keep the temperature constant for a long time is to put the pan with water into the oven and use the thermostat of the oven.</p>
<p><img id="image88" src="http://blog.khymos.org/wp-content/2007/01/meat-plastic-bag-in-water.jpg" alt="meat in plasticbag, water at 59 C" /></p>
<p>4. Heat a frying pan, add a fat of you choice, remove meat from plastic bag and brown both sides of the meat. Since you take the meat directly from the water bath it&#8217;s already at about 60 °C. Therefore the browning is very fast.</p>
<p><img id="image84" src="http://blog.khymos.org/wp-content/2007/01/meat-in-frying-pan.jpg" alt="meat-in-frying-pan" /></p>
<p>5. A temperature of 60 °C (140 F) gives the meat a pink interior. It&#8217;s succulent and juicy. The short frying gives it a nice browned crust and the chewing resistance is perfect. All in all a wonderful combination of taste, aroma, texture and mouth feel!</p>
<p><img id="image85" src="http://blog.khymos.org/wp-content/2007/01/meat-interior.jpg" alt="meat-interior" /></p>
<p><strong>Note added January 2009:</strong><br />
Since I published this procedure the first time I&#8217;ve learnt a lot more about sous vide. The procedure above is a rather crude procedure, but it works. If the meat turns out grey you&#8217;ll need to turn the temperature somewhat down. If you&#8217;re interested in reading more about sous vide, the best discussion I know of which also includes important safety aspects is Douglas Baldwin&#8217;s <a href="http://www.douglasbaldwin.com/sous-vide.html">&#8220;A Practical Guide to Sous Vide Cooking&#8221;</a>. </p>
<p><strong>Related posts:</strong><br />
<a href="http://blog.khymos.org/2009/01/18/a-mathematician-cooks-sous-vide/">A mathematician cooks sous vide</a><br />
<a href="http://blog.khymos.org/2008/12/14/sous-vide-cooking-joy/">Sous vide cooking joy</a><br />
<a href="http://blog.khymos.org/2008/12/12/santa-came-early-this-year/">Santa came early this year</a><br />
<a href="http://blog.khymos.org/2008/06/25/upcoming-books-on-sous-vide/">Upcoming books on sous vide</a></p>
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