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	<title>blog.khymos.org &#187; odor activity value</title>
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	<link>http://blog.khymos.org</link>
	<description>- dedicated to molecular gastronomy</description>
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		<title>TGRWT #18: Plum and blue cheese</title>
		<link>http://blog.khymos.org/2009/08/02/tgrwt-18-plum-and-blue-cheese/</link>
		<comments>http://blog.khymos.org/2009/08/02/tgrwt-18-plum-and-blue-cheese/#comments</comments>
		<pubDate>Sun, 02 Aug 2009 20:28:42 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[aroma index]]></category>
		<category><![CDATA[blue cheese]]></category>
		<category><![CDATA[dessert]]></category>
		<category><![CDATA[foodpairing]]></category>
		<category><![CDATA[Gorgonzola]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[key odorants]]></category>
		<category><![CDATA[odor activity value]]></category>
		<category><![CDATA[odour unity value]]></category>
		<category><![CDATA[plum]]></category>
		<category><![CDATA[prunus prunus]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=1711</guid>
		<description><![CDATA[Finally it&#8217;s time for a new round of TGRWT. It&#8217;s the 18th round and the host this time is Aidan Brooks, a trainee chef who works in Spain. In his blog he&#8217;s touched upon flavor pairing several times and also wrote a blog post on the same topic for &#8220;Word of mouth&#8221;, the food blog [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2009/08/tgrwt-18-620x415.png" alt="tgrwt-18" title="tgrwt-18" width="620" height="415" class="alignnone size-large wp-image-1715" /></p>
<p>Finally it&#8217;s time for a new round of <a href="http://blog.khymos.org/tgrwt/">TGRWT</a>. It&#8217;s the 18th round and the host this time is Aidan Brooks, a trainee chef who works in Spain. In his <a href="http://www.aidanbrooks.blogspot.com/">blog</a> he&#8217;s touched upon flavor pairing several times and also wrote a <a href="http://www.guardian.co.uk/lifeandstyle/wordofmouth/2008/mar/06/atasteofhoneywithpepperp">blog post on the same topic</a> for <a href="http://blogs.guardian.co.uk/food/">&#8220;Word of mouth&#8221;</a>, the food blog of <a href="http://www.guardian.co.uk/">The Guardian</a>. The foods to pair this time are <strong>plum and blue cheese</strong>, and as usual you can read more about how to participate in the <a href="http://aidanbrooks.blogspot.com/2009/07/announcing-they-go-really-well-together.html">announcement post</a>. The deadline for submissions is September 1st.</p>
<p><a href="http://blog.khymos.org/tgrwt/">TGRWT</a> is not a competition, but Aidan wanted to add a little <a href="http://aidanbrooks.blogspot.com/2009/07/announcing-they-go-really-well-together.html">competitive element</a> to round of the meal. <span id="more-1711"></span>So his challenge to you (in addition to the normal TGRWT contributions) is to make a dessert using plum and blue cheese which additionally incorporates any two of the following flavors: salty, sour, bitter, umami, pungent, astringent. He will pick a winner and the prize is quite cool: <strong>he&#8217;ll make a restaurant level version of it</strong>, with the name of the winner incorporated in the title of the dish and try to get this on the menu at Restaurante Ferrero where he works as a Pastry Chef on the team of Paco Morales, Spain&#8217;s &#8220;Chef of the Year 2009&#8243;. </p>
<p><img src="http://blog.khymos.org/wp-content/2009/08/plums-1064932243_d118bf9b4a_o-620x620.jpg" alt="plums-1064932243_d118bf9b4a_o" title="plums-1064932243_d118bf9b4a_o" width="620" height="620" class="alignnone size-large wp-image-1722" /><br />
<em><a href="http://www.flickr.com/photos/opengallery/1064932243/">Photo</a> by <a href="http://www.flickr.com/photos/opengallery/">mykrar</a> from flickr.com (<a href="http://creativecommons.org/licenses/by-nc/2.0/">CC BY-NC 2.0</a>)</em></p>
<p>Regarding the chemistry behind this pairing there is (for once) actually some informartion available. From a <a href="http://dx.doi.org/10.1017/S0022029900004106">paper</a> on gorgonzola I&#8217;ve learnt that 2-nonanone, 1-octen-3-ol, 2-heptanol, ethyl hexanoate, methylanisole and 2-heptanone are the most important impact odorants of natural and creamy Gorgonzola cheese [1]. For plums I haven&#8217;t found anything on impact odorants in fresh plums, but there is a <a href="http://dx.doi.org/10.1016/j.foodchem.2008.05.003">paper</a> on impact odorants in candied plums [2], and comparing the two papers I find that <strong>phenyl acetaldehyde, ethyl benzoate and ethyl octanoate are present in both Gorgonzola cheese and candied plums</strong> and have odor activity values greater than 1. There&#8217;s another <a href="http://dx.doi.org/10.1002/jsfa.2740650116">paper</a> as well comparing two plum varieties were the abstract mentions odor unit values, but alas &#8211; I don&#8217;t have access to the full text (maybe someone with access could check it and give me a hint about the impact odorants?) [3]. There are probably some differences between fresh and candied plums, but at least this shows that you&#8217;re safe if you want to use candied plums when cooking up something with blue cheese.</p>
<p><img src="http://blog.khymos.org/wp-content/2009/08/plum-gorgonzola-impact-odorants.png" alt="plum-gorgonzola-impact-odorants" title="plum-gorgonzola-impact-odorants" width="400" height="259" class="alignnone size-full wp-image-1719" /></p>
<p>[1] Moio, L.; Piombiono, P.; Addeo F. <em>J. Dairy Research</em> <strong>2000</strong>, 67, 273 &#8220;Odour-impact compounds of Gorgonzola cheese&#8221;. DOI: <a href="http://dx.doi.org/10.1017/S0022029900004106">10.1017/S0022029900004106</a><br />
[2] Nunes, C.; Coimbra, M. A.; Saraiva, J.; Rocha, S. M. <em>Food Chemistry</em> <strong>2008</strong>, 111, 897 &#8220;Study of the volatile components of a candied plum and estimation of their contribution to the aroma&#8221;. DOI: <a href="http://dx.doi.org/10.1016/j.foodchem.2008.05.003">10.1016/j.foodchem.2008.05.003</a><br />
[3] Gómez, E.; Ledbetter, C. A. J. of the Science of Food and Agriculture 2006, 65 (1), 111. &#8220;Comparative study of the aromatic profiles of two different plum species: Prunus salicina Lindl and Prunus simonii L&#8221;. DOI: <a href="http://dx.doi.org/10.1002/jsfa.2740650116">10.1002/jsfa.2740650116</a></p>
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		<item>
		<title>French book on flavor pairing of food and wine</title>
		<link>http://blog.khymos.org/2009/07/22/french-book-on-flavor-pairing-of-food-and-wine/</link>
		<comments>http://blog.khymos.org/2009/07/22/french-book-on-flavor-pairing-of-food-and-wine/#comments</comments>
		<pubDate>Wed, 22 Jul 2009 18:21:50 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[blogs]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[websites]]></category>
		<category><![CDATA[Bordeaux]]></category>
		<category><![CDATA[cinnamon]]></category>
		<category><![CDATA[curry]]></category>
		<category><![CDATA[food pairing]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[key odorants]]></category>
		<category><![CDATA[lamb]]></category>
		<category><![CDATA[Languedoc]]></category>
		<category><![CDATA[oak]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor]]></category>
		<category><![CDATA[odor activity value]]></category>
		<category><![CDATA[Pinot noir]]></category>
		<category><![CDATA[pork]]></category>
		<category><![CDATA[red wine]]></category>
		<category><![CDATA[rosemary]]></category>
		<category><![CDATA[Sauvignon blanc]]></category>
		<category><![CDATA[wine]]></category>
		<category><![CDATA[wine pairing]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=1691</guid>
		<description><![CDATA[The Canadian sommerlier François Chartier (he has an extensive website featuring several blogs, including a section named Sommellerie moléculaire) is out with a new book on food and wine pairing. It&#8217;s not just another (superfluous) book on the subject. As the title Papilles et molécules (= Tastebuds and Molecules, unfortunately not available in English) suggests [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2009/07/papilles_molecules.jpg" alt="papilles_molecules" title="papilles_molecules" width="500" height="497" class="alignnone size-full wp-image-1695" /></p>
<p>The Canadian sommerlier François Chartier (he has an extensive <a href="http://www.francoischartier.ca/">website</a> featuring several blogs, including a section named <em><a href="http://www.francoischartier.ca/sommellerie-moleculaire">Sommellerie moléculaire</a></em>) is out with a new book on food and wine pairing. It&#8217;s not just another (superfluous) book on the subject. As the title <em><a href="http://www.amazon.ca/PAPILLES-MOLÉCULES-SCIENCE-AROMATIQUE-ALIMENTS/dp/2923681061">Papilles et molécules</a></em> (= Tastebuds and Molecules, unfortunately not available in English) suggests there is some science involved. It turns out in fact that <strong>he has applied the principles of flavor pairing to food and wine</strong>. With help from Richard Béliveau from Agriculture and Agri-Food Canada and Martin Loignon from PerkinElmer he has analyzed wines and food and comes up with the following suggestions for lamb, as described in the article <a href="http://www.theglobeandmail.com/life/food-and-wine/chemistry-set-wine-pairing/article1218269/">&#8220;Chemistry-set wine pairing&#8221;</a>:<br />
<span id="more-1691"></span></p>
<blockquote><p>Having roast lamb? Don&#8217;t waste it on an ill-advised red Bordeaux, the old standby trotted out by generations of sommeliers. Lamb&#8217;s characteristic flavour comes from <a href="http://en.wikipedia.org/wiki/Thymol">thymol</a>, an aromatic compound found in the oil of, yes, thyme. It&#8217;s also a flavour note associated with red wines from the southern Languedoc region of France, such as Minervois, Corbières or St. Chinian.</p></blockquote>
<p>Other combinations mentioned in the <a href="http://www.theglobeandmail.com/life/food-and-wine/chemistry-set-wine-pairing/article1218269/">article</a> include:</p>
<p>rosemary &#8211; white wines from northern Alsace<br />
pork &#8211; oaked red wines<br />
curries &#8211; viognier<br />
cinnamon &#8211; pinot noir, grenache, ice cider, oloroso sherry</p>
<p>François Chartier also introduces &#8220;bridge ingredients&#8221;. Mint, which goes well with sauvignon blanc, shares aroma compounds with parsley, fennel and tarragon. Based on this he theorizes that sauvignon blanc should also pair well with dishes based on these ingredients. </p>
<p>As far as I can see (with my very limited high school French) <strong>there are no links or references to all the other activities in the field</strong>: Heston Blumenthal&#8217;s pioneering of the concept together with François Benzi from Firmenich, the Food pairing website &#8211; not even to the TGRWT food blogging event <img src='http://blog.khymos.org/wp-includes/images/smilies/icon_smile.gif' alt=':)' class='wp-smiley' />  Nevertheless it&#8217;s nice to see that the concept has now been applied to food and wine as well. As I don&#8217;t own the book yet I can&#8217;t tell whether François Chartier includes odor activity values in his discussion or not (but I certainly hope he does!).</p>
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		<slash:comments>6</slash:comments>
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		<title>The Flemish Primitives: A travel report (part 1)</title>
		<link>http://blog.khymos.org/2009/01/09/the-flemish-primitives-a-travel-report-part-1/</link>
		<comments>http://blog.khymos.org/2009/01/09/the-flemish-primitives-a-travel-report-part-1/#comments</comments>
		<pubDate>Fri, 09 Jan 2009 00:01:51 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[Andrew Dornenburg]]></category>
		<category><![CDATA[Ben Roche]]></category>
		<category><![CDATA[Bernard Lahousse]]></category>
		<category><![CDATA[food pairing]]></category>
		<category><![CDATA[Heston Blumenthal]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[Karen Page]]></category>
		<category><![CDATA[Nicholas Kurti]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>
		<category><![CDATA[Peter Barham]]></category>
		<category><![CDATA[Tony Conigliaro]]></category>
		<category><![CDATA[travel report]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=554</guid>
		<description><![CDATA[I had a wonderful trip to Brugge/Bruges to attend the foodpairing seminar The Flemish Primitives. I got to meet many interesting people including Heston Blumenthal, Peter Barham, Andrew Dornenburg, Karen Page, Ben Roche and Tony Conigliaro to mention a few. I also finally had the opportunity to talk to my fellow Swedish food bloggers Lisa [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2009/01/brugge.jpg" alt="" title="brugge" width="450" height="450" class="alignnone size-full wp-image-559" /></p>
<p>I had a wonderful trip to Brugge/Bruges to attend the foodpairing seminar <a href="http://www.theflemishprimitives.com/">The Flemish Primitives</a>. I got to meet many interesting people including <a href="http://en.wikipedia.org/wiki/Heston_Blumenthal">Heston Blumenthal</a>, <a href="http://en.wikipedia.org/wiki/Peter_Barham">Peter Barham</a>, <a href="http://en.wikipedia.org/wiki/Andrew_Dornenburg">Andrew Dornenburg</a>, <a href="http://en.wikipedia.org/wiki/Karen_A._Page">Karen Page</a>, <a href="http://en.wikipedia.org/wiki/Moto_(restaurant)">Ben Roche</a> and <a href="http://en.wikipedia.org/wiki/Tony_Conigliaro_(mixologist)">Tony Conigliaro</a> to mention a few. I also finally had the opportunity to talk to my fellow Swedish food bloggers <a href="http://taffel.se/medarbetare/lisa-forare-winbladh">Lisa Förare Winbladh</a> (<a href="http://matalskaren.taffel.se/">Matälskaren</a>, Swedish only but <a href="http://translate.google.com/translate?hl=no&#038;u=http%3A%2F%2Fmatalskaren.taffel.se%2F&#038;sl=sv&#038;tl=en">Google can translate</a>) and <a href="http://taffel.se/medarbetare/malin-sandstrom">Malin Sandström</a> (<a href="http://matmolekyler.taffel.se/">Matmolekyler</a>, Swedish only but <a href="http://translate.google.com/translate?hl=no&#038;u=http%3A%2F%2Fmatmolekyler.taffel.se%2F&#038;sl=sv&#038;tl=en">Google can translate</a>) who&#8217;ve recently been awarded money to write a Swedish book about molecular gastronomy for home cooks. I even talked to several people who read Khymos! It&#8217;s always nice when I can attach some faces to the crowd out there in the big, unpersonal blogosphere.</p>
<p>As you see from this long post the day was packed and believe it or not &#8211; there will be a couple <strong>more posts in the next few days</strong>. One on the surprise &#8220;chocolate box&#8221; (for me this was the highlight), a summary of the interview with Heston Blumenthal and some info on the chemistry behind the <strong>glowing lollipops</strong>! I&#8217;ll also try do dig up the recipe for the chocolate dip that came with our lunch fries.<br />
<span id="more-554"></span><br />
<img src="http://blog.khymos.org/wp-content/2009/01/peter-barham.jpg" alt="" title="peter-barham" width="450" height="450" class="alignnone size-full wp-image-560" /><br />
<em>In case you wondered: Peter </em>always<em> wears penguins!</em></p>
<p>Peter Barham (physicist, author of <a href="http://www.amazon.com/exec/obidos/ASIN/3540674667/kjemiihverdao-20">The science of cooking</a>) started the day by giving an introduction to the <strong>scientific approach to cooking</strong>. Cooking started a lot of science, and chemistry (and alchemy) has origins that can be traced back to the observation of how food changed when cooked. And as a side note: even the word chemistry is linked to food through the greek word <a href="http://khymos.org">Khymos</a> <img src='http://blog.khymos.org/wp-includes/images/smilies/icon_smile.gif' alt=':)' class='wp-smiley' />  Until about 100 years ago there was a clear link between cooking and chemistry, but then came a period where scientists mostly did not bother much about food. Until Nicholas Kurti entered the scene: that&#8217;s the guy who said that <em>&#8220;I think it is a sad reflection on our civilization that while we can and do measure the temperature in the atmosphere of Venus we do not know what goes on inside our soufflés&#8221;</em>. Four examples were used to illustrate how science can help chefs. </p>
<p>1) Conflicting reasons are given for <strong>why salt should be added to blanching water</strong> to retain the green color of vegetables. Contrary to popular belief salt does not raise the boling temperature of the water with more than a fraction of a degree. Science tells us that there really <a href="http://www.rsc.org/education/teachers/learnnet/kitchenchemistry/01.htm">isn&#8217;t any good reason for adding salt</a> to the water when blanching vegetables. </p>
<p>2) Science also provides insight to <strong>what happens when we heat up meat</strong>. When heated the meat first gets tougher. At around 40-45 °C the meat proteins start to denature, and at 55 °C the meat goes from tender to tough. Prolonged heating above 55 °C however will cause the collagen to dissolve into soft gelatin.</p>
<p>3) Thanks to science we now have a vide range of gelling agents (or hydrocolloids if you like) available for use in the kitchen. They can be used to create gels that are hard, soft, tough, elastic, brittle, hot and so on. We can also explain the crunchy and crispy texture of caramel which technically is classified as a &#8220;glass&#8221;. And we can also <strong>understand why ice cream has such a soft texture</strong>. This has to do with the very small size of the solid particles in ice cream (they&#8217;re typically < 1/10 mm). And a very nice way of achieving this is by making the ice cream with liquid nitrogen so it freezes very fast.</p>
<p>4) Science helps us understand what flavor is and how <strong>we perceive flavor using all our senses</strong>. For instance our memory plays an important role when our brain interprets a flavor. Your history of eating will influence how your next meal tastes! Sight is also extremely important. This can easily be demonstrated with some white wine and blue/red food coloring. If an unsuspecting subject is asked to describe &#8220;white&#8221; white wine and white wine colored with blue and red food coloring the descriptions will probably be typical of a white and red wine. Even if you know your are drinking a red colored white wine it is hard to believe that it is the same wine. The color of plates also influences our perception of flavor, so most people find eating from a blue plate unpleasant. Sound influences how we chew and a crunchy sound actually stops our jaws from closing to fast. If the chewing sound is played back with a 0.5 second delay it is almost impossible to eat! It has also been shown that the beat of music influences how fast guests chew, and apparently there is a restaurant in Australia that utilizes this. It has also long been known that touching sand paper or smooth skin can affect the texture of what we eat.</p>
<p><a href='http://blog.khymos.org/wp-content/2009/01/dornenburg-page.jpg'><img src="http://blog.khymos.org/wp-content/2009/01/dornenburg-page.jpg" alt="" title="dornenburg-page" width="450" height="450" class="alignnone size-full wp-image-558" /></a><br />
<em>Andrew Dornenburg and Karen Page</em></p>
<p>Next up were Karen Page and Andrew Dornenburg who presented several of their bestselling books on cooking and flavor, including <a href="http://www.amazon.com/exec/obidos/ASIN/0471287857/kjemiihverdao-20">Culinary Artistry</a>, <a href="http://www.amazon.com/exec/obidos/ASIN/0821257188/kjemiihverdao-20">What to Drink With What you Eat</a> and <a href="http://www.amazon.com/exec/obidos/ASIN/0316118400/kjemiihverdao-20">The Flavor Bible</a>. They made an important point that cooking is the sum of ingredients and technique/preparation. Food science and molecular gastronomy has provided a lot of information on technique, and the example par excellence is Harold McGee&#8217;s <a href="http://www.amazon.com/exec/obidos/ASIN/0684800012/kjemiihverdao-20">On food and cooking</a>. However, for ingredients and flavor pairing in particular there hasn&#8217;t been any authoritative source available, forcing chefs to cross read a number of cookbooks when looking for new flavors and pairings. It was this realization that motivated them to write <a href="http://www.amazon.com/exec/obidos/ASIN/0471287857/kjemiihverdao-20">Culinary Artistry</a> which is really <strong>a thesaurus of classic pairings</strong>. I can testify to it&#8217;s usefulness &#8211; and one example I&#8217;ve presented here on the blog are the cherry jams I made with pepper and other spices. Their most recent book, <a href="http://www.amazon.com/exec/obidos/ASIN/0316118400/kjemiihverdao-20">The Flavor Bible</a>, is an updated and expanded edition of <a href="http://www.amazon.com/exec/obidos/ASIN/0471287857/kjemiihverdao-20">Culinary Artistry</a> which includes and reflects the changes in consumer preference in the last decade.</p>
<p>I have emailed a litte with Karen and Andrew previously and got the opportunity to chat with them in the break. &#8211; We&#8217;re excited to learn about new approaches to flavor pairing, Karen let me know. Andrew added that they hadn&#8217;t had the opportunity yet to sample molecularily based food pairings before so they we&#8217;re looking forward to try this.</p>
<p>Lorenzo Cerretoni gave a presentation about flavor compounds in olive oil and how they can be paired with Mantis shrimp. After this informative, yet slightly less inspiring talk the Belgian chef Bart de Pooter presented his 4 taste model and how he uses this as a creative approach to create dishes and menus. One concept he promoted was to use ingredients from the same environment. A pheasant for instance walks on grass and eats maize and carrot, so naturally it could also be served together with flavors such as grass, maize and carrot. He also talked about physical and psychic needs and gave a slightly wrong explanation of the flavor pairing hypothesis.</p>
<p>In fact during the whole day there was <strong>no proper scientific explanation and discussion</strong> of the hypothesis, but Bernard Lahousse &#8211; project leader of The Flemish Primitives &#8211; did give <strong>a popularized version of the hypothesis</strong> and an <strong>account of how it all started</strong>. He explained how the Firmenich scientist François Benzi first stubled across a new way of pairing foods. At one of the Erice meetings he smelled jasmin in a garden and being a flavor scientist knew that this smell was mainly due to indole. Knowing that pork liver also smells of indole he got the idea that <strong>jasmine and pork liver</strong> might taste nice together &#8211; and they did! Bernard did show a picture of a GC-MS and explained how the University of Leuven has been doing food analyses and that only odors with concentrations above the odor thresholds were taken into account. Since he didn&#8217;t mention odor activity values (OAV) specifically I asked Bernard about that later and he confirmed that all the data in the <a href="http://www.foodpairing.be/">food pairing website</a> are now based on odor activity values. Since the first version of the food pairing web site was based on concentration and number of odorants I would expect that this would change some of the pairing charts and Bernard confirmed that this had been the case. </p>
<p>For the event 10 chefs where each given a food product from one of the sponsors. These products were then analyzed and a list of suggested pairings was provided to all the chefs. It should be mentioned that these were top class chefs, but I have to admit that <strong>watching chefs cook in real time actually became quite boring after a while</strong>, especially since some of the dishes needed seemingly endless steps of preparation. For most of the preparations presented it was also very unclear which of the ingredients used were picked based on the flavor pairing and which were picked by the chef to complete the dish. But the dishes looked absolutely wonderful! Too bad we couldn&#8217;t sample them <img src='http://blog.khymos.org/wp-includes/images/smilies/icon_smile.gif' alt=':)' class='wp-smiley' />  <strong>I found two of the dishes particularily interesting</strong> (and I think the recipes will be made available on the web). Sang Hoon Degeimbre, chef at <a href="http://www.airdutemps.be/">L&#8217;Air du temps</a> had chosen Leffe beer, but instead of doing a flavor pairing he did a <a href="http://www.foodpairing.be/QuickTour.aspx">flavor substitution</a>. To achieve this he used several ingredients (shown in the figure below) which when combined would resemble Leffe. In fact he made a dish completely without Leffe that was intented to taste like Leffe &#8211; it&#8217;s hard to say whether he succeeded or not, but the concept is very interesting! And what warmed the heart of an organic chemist was that Sang Hoon had equipped his kitchen with an erlenmeyer flask and used a glass syringe (looked like a luer lock Hamilton type syringe to me).</p>
<p><img src="http://blog.khymos.org/wp-content/2009/01/leffe-substitution.png" alt="" title="leffe-substitution" width="450" height="450" class="alignnone size-full wp-image-556" /><br />
<em>Figure from <a href="http://www.foodpairing.be">food pairing website</a>. (C) Creax 2008.</em></p>
<p>The food pairing I found most interesting was the one with Oud Brugge (a cheese), coffee and vanilla. To bind these flavors together chef Gert de Mangeleer from <a href="http://www.hertog-jan.com/">Hertog Jan</a> used potatoes. The surprising element of the dish was the coffee &#8211; he sprinkled his dish with freshly ground coffee. The vanilla was applied as a grape seed oil extract of natural vanilla &#8211; a nice example of how <a href="http://blog.khymos.org/2008/10/24/wonders-of-extraction-oil/">oil can be used for flavor extraction</a>. </p>
<p><img src="http://blog.khymos.org/wp-content/2009/01/ben-roche-scene.jpg" alt="" title="ben-roche-scene" width="450" height="450" class="alignnone size-full wp-image-557" /><br />
<em>Ben sitting on the stage watching his own video.</em></p>
<p>- If Einstein had been a chef, he&#8217;d probably be like Ben Roche, said presenter Gene Bervoets. Ben is the pastry chef at Homaro Cantu&#8217;s <a href="http://www.motorestaurant.com/">Moto</a> restaurant in Chicago &#8211; it&#8217;s the restaurant where you can chose between a 10 and 20 course menu and then start your meal by eating the menu. Ben&#8217;s topic was the <strong>Chicago style hot dog</strong> and he started off by presenting a mind map of this, resembling the food pairing charts at the food pairing website. Most of his presentation was in fact prerecorded video clips which were really entertaining! His deconstruction/construction of the Chicago style hot dog resulted in a chips &#038; salsa. Evolution of flavor turned the hot dog into pop corn (&#8220;less calories than when eating the hot dog&#8221;) sprayed with hot dog infused oil and sprinkled with freeze dried garnish. Translation of culture resulted in a Mexican version of &#8220;encased meat&#8221; using chorizo and a soft taco shell. This dish was also made into a dessert version. Lastly the hot dog was transmogrified into a cartoon dessert version with strawberry sorbet, mint and pistacchios. Hopefully the videos will be made available, but in the mean time you can check out the <a href="http://www.youtube.com/watch?v=ykWNHXfcL20">video</a> of Ben at Taste3.</p>
<p><img src="http://blog.khymos.org/wp-content/2009/01/food-pairing-samples.jpg" alt="" title="food-pairing-samples" width="450" height="450" class="alignnone size-full wp-image-562" /></p>
<p>Although we couldn&#8217;t sample the chef&#8217;s preparations there a number of tasting samples of different food pairings available in the breaks:</p>
<li>goose liver terrine, escabeche of shitake and pepper</li>
<li>almond thins, mozzarella, figs and ham</li>
<li>cucumber, salmon confit, orange and soy milk</li>
<li>chocolate, white boudain, cauliflower and avocado massala</li>
<li>potatoes, buttermilk, spring onions and shrimp</li>
<li>grilled chicken, red pepper coulis, raw ginger and lime</li>
<li>baked beef, cream of peas, peanuts and vinagrette with 70% chocolate</li>
<li>rye bread, blue cheese and pineapple</li>
<li>potatoe cream, coffee, vanilla and cheese</li>
<p>Of these my favorites were the almond thins with mozzarella, fig and ham, and the cooked beef with peanut, chocolate vinagrette and peas. The potato cream was nice, but was a litle overpowered by to much cheese.</p>
<p><img src="http://blog.khymos.org/wp-content/2009/01/beef-chocolate.jpg" alt="" title="beef-chocolate" width="450" height="450" class="alignnone size-full wp-image-561" /><br />
<em>Baked beef, cream of peas, peanuts and vinagrette with 70% chocolate</em></p>
<p>The program session was closed by Albert Adria, younger brother of Ferran Adria. He showed stunning pictures from his coming book natura, accompanied by videos showing how the different elements of the dishes are created. He also showed a short teaser documentary for <a href="http://www.amazon.com/exec/obidos/ASIN/0714848832/kjemiihverdao-20">A day at el Bulli</a>. </p>
<p>Next year&#8217;s meeting will be devoted to tools, including one which was presented at the very end of the day with music, ballet dancers and fire works: <a href="http://q2.rvbid.be/">a reinvention of Ford&#8217;s assembly line for mass production of haute cuisine</a>.</p>
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		<title>TGRWT #12: Chanterelle and apricot</title>
		<link>http://blog.khymos.org/2008/11/04/tgrwt-12-chanterelle-and-apricot/</link>
		<comments>http://blog.khymos.org/2008/11/04/tgrwt-12-chanterelle-and-apricot/#comments</comments>
		<pubDate>Mon, 03 Nov 2008 23:05:27 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[apricot]]></category>
		<category><![CDATA[chanterelle]]></category>
		<category><![CDATA[food blogging event]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=505</guid>
		<description><![CDATA[Tri-2-cook has announced the foods to pair in the twelfth round of &#8220;They go really well together&#8221; (or TGRWT for short): apricot and chanterelle. More information on how to participate can be found in the announcement post. If the ingredients are out of season where you live, remember that you can use ingredients that are [...]]]></description>
			<content:encoded><![CDATA[<p><a href='http://blog.khymos.org/wp-content/2008/11/tgrwt-12.png'><img src="http://blog.khymos.org/wp-content/2008/11/tgrwt-12.png" alt="" title="tgrwt-12" width="450" height="302" class="alignnone size-full wp-image-506" /></a></p>
<p><a href="http://tri-2-cook.blogspot.com/2008/10/tgrwt-12-chanterelle-and-apricot.html">Tri-2-cook</a> has announced the foods to pair in the twelfth round of &#8220;They go really well together&#8221; (or TGRWT for short): <strong>apricot and chanterelle</strong>. More information on how to participate can be found in the <a href="http://tri-2-cook.blogspot.com/2008/10/tgrwt-12-chanterelle-and-apricot.html">announcement</a> post. If the ingredients are out of season where you live, remember that you can use ingredients that are dried, canned or preserved. The heating and/or air exposure can of course alter the flavor composition, but it&#8217;s still worth giving it a try. </p>
<p>Regarding the chemistry behind this flavor pairing I&#8217;ve found the following. Based on quantitative measurements <a href="http://dx.doi.org/10.1021/jf0705015">Greger and Schieberle</a> identified 18 compounds with odor activity values (OAVs) greater than 1 in apricot (<em>Prunus armeniaca</em>). I have not been able to locate any studies of chanterelle (<em>Cantharellus cibarius</em>) with OAV values, but there are a couple of articles which list <a href="http://dx.doi.org/10.1021/jf073181y ">volatile</a> <a href="http://www.cefe.cnrs.fr/subnamed/pdf/rapior/Fons2003CryptoMycolCantharellus.pdf">compounds</a>. Comparing these lists with the OAV data for apricots there is not much overlap. The only compounds which had an OAV > 1 in apricots and were also found in chanterelle are <strong>1-octen-3-one</strong> (OAV in apricot = 55) and <strong>hexanal</strong> (OAV in apricot = 15) shown in the figure below. </p>
<p><a href='http://blog.khymos.org/wp-content/2008/11/apricot-chanterelle.png'><img src="http://blog.khymos.org/wp-content/2008/11/apricot-chanterelle-300x254.png" alt="" title="apricot-chanterelle" width="300" height="254" class="aligncenter size-medium wp-image-507" /></a></p>
<p>It&#8217;s interesting to note that OAV studies often come with certain surprises regarding flavor compounds. As <a href="http://dx.doi.org/10.1021/jf0705015">Greger and Schieberle</a> point out in their abstract:</p>
<blockquote><p>certain lactones, often associated with an apricot aroma note, such as gamma-undecalactone, gamma-nonalactone, and delta-decalactone, showed very low OAVs (<5) (...)  Omission experiments indicated that previously unknown constituents of apricots, such as (E,Z)-2,6-nonadienal or (Z)-1,5-octadien-3-one, are key contributors to the apricot aroma.</p></blockquote>
<p>Some compounds that are present at higher concentrations are less important because they have a high odor threshold, whereas other compounds which are present in minute quantities play important roles because we can detect them at very low concentrations. Once again this shows how important it is to use OAV values when looking for flavor pairings!</p>
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		<title>TGRWT #9: Parmesan and cocoa</title>
		<link>http://blog.khymos.org/2008/02/09/tgrwt-9-parmesan-and-cocoa/</link>
		<comments>http://blog.khymos.org/2008/02/09/tgrwt-9-parmesan-and-cocoa/#comments</comments>
		<pubDate>Sat, 09 Feb 2008 11:30:25 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2008/02/09/tgrwt-9-parmesan-and-cocoa/</guid>
		<description><![CDATA[It&#8217;s time for a new round of food pairing! Robert of lamiacucina is hosting TGRWT #9 and the foods to pair this time are parmesan and cocoa. I&#8217;ve previously blogged about this combination and odor activity values (OAV) are available for both parmesan and cocoa. These are the molecules that significantly impact the odor of [...]]]></description>
			<content:encoded><![CDATA[<p><img src='http://blog.khymos.org/wp-content/2008/02/tgrwt-9.png' alt='tgrwt-9.png' /></p>
<p>It&#8217;s time for a new round of food pairing! Robert of <a href="http://lamiacucina.wordpress.com">lamiacucina</a> is hosting <a href="http://lamiacucina.wordpress.com/2008/02/04/tgrwt-9-parmesan-and-cocoa/">TGRWT #9</a> and the foods to pair this time are parmesan and cocoa. I&#8217;ve <a href="http://blog.khymos.org/2007/05/05/two-flavour-pairing-case-studies/">previously blogged about this combination</a> and odor activity values (OAV) are available for both parmesan and cocoa. These are the molecules that significantly impact the odor of both parmesan and cocoa:</p>
<p><img src='http://blog.khymos.org/wp-content/2008/02/parmesan-cocoa-volatiles.png' alt='parmesan-cocoa-volatiles.png' /></p>
<p>Don&#8217;t forget to check out Chad&#8217;s <a href="http://chadzilla.typepad.com/chadzilla/2008/02/trgwt-8-roundup.html">roundup of TGRWT #8</a> where several professional chefs participated!</p>
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		<title>TGRWT #8: White chocolate soufflé with caviar</title>
		<link>http://blog.khymos.org/2008/01/30/tgrwt-8-white-chocolate-souffle-with-caviar/</link>
		<comments>http://blog.khymos.org/2008/01/30/tgrwt-8-white-chocolate-souffle-with-caviar/#comments</comments>
		<pubDate>Wed, 30 Jan 2008 20:49:56 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[tips & tricks]]></category>
		<category><![CDATA[egg]]></category>
		<category><![CDATA[eggs]]></category>
		<category><![CDATA[Hervé This]]></category>
		<category><![CDATA[Heston Blumenthal]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>
		<category><![CDATA[techniques]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2008/01/30/tgrwt-8-white-chocolate-souffle-with-caviar/</guid>
		<description><![CDATA[As a late (but just in time for the deadline) response to TGRWT #8 which was announced by Chadzilla in December last year &#8211; here is finally my write up on a recipe and a little on the background of this flavor combination which has become a classic in molecular gastronomy. Heston Blumenthal introduced it [...]]]></description>
			<content:encoded><![CDATA[<p><img src='http://blog.khymos.org/wp-content/2008/01/white-chocolate-caviar-2.jpg' alt='white-chocolate-caviar-2.jpg' /></p>
<p>As a late (but just in time for the deadline) response to TGRWT #8 which was announced by <a href="http://chadzilla.typepad.com/chadzilla/2007/11/tgrwt.html">Chadzilla</a> in December last year &#8211; here is finally my write up on a recipe and a little on the background of this flavor combination which has become a classic in molecular gastronomy. </p>
<p>Heston Blumenthal introduced it around 2002 at The Fat Duck. It&#8217;s well worth reading what Heston <a href="http://www.guardian.co.uk/weekend/story/0,,708669,00.html">wrote</a> about this combination back then. He describes how salt can help bring out the flavor of many desserts. At one point he tried caviar and white chocolate &#8211; the effect was stunning. He then wanted to find out why this combination was so successful:</p>
<blockquote><p>I gave some caviar and chocolate to François Benzi, who works for Firmenich, the flavourings and perfumes company based in Geneva. He was so surprised at the way that the caviar and chocolate melded together that he excused himself for half an hour while he tried to discover the reason behind the success of this union. </p>
<p>When he returned, the response was that both the chocolate and caviar contain high levels of amines. These are a group of proteins that have broken down from their amino acid state but not so far as to become ammonia. Amines contribute to the desirable flavours that we find in cooked meats and cheeses, among other things.</p></blockquote>
<p>Some might object to using caviar but remember that there is no need to turn to <a href="http://en.wikipedia.org/wiki/Sturgeon">sturgeon</a> caviar as this species is endangered. I used caviar from <a href="http://en.wikipedia.org/wiki/Capelin">Capelin</a> which costs less than $4/€3 for a box of 50 g. As I have never tasted the &#8220;real&#8221; stuff I&#8217;m not the right person to judge about similarity or difference in aroma. And in case you also wondered about the terminology &#8211; roe is the fully ripe egg masses of fish whereas caviar refers to processed, salted roe. I decided to make a soufflé and based the recipe loosely on one of the soufflé recipes in my <a href="http://www.amazon.com/exec/obidos/ASIN/0609609718/kjemiihverdao-20">Larousse Gastronomique</a>.</p>
<p><img src='http://blog.khymos.org/wp-content/2008/01/white-chocolate-caviar-3.jpg' alt='white-chocolate-caviar-3.jpg' /></p>
<p><strong>White chocolate soufflé with caviar</strong><br />
40 g white chocolate<br />
30 g flour<br />
1 dL milk<br />
35 g caviar<br />
3 eggs, separated<br />
nutmeg</p>
<p>Melt chocolate on very low heat. Add 1/3 of the flour and stir, heating gently. Add a 1/3 of the milk and mix thoroughly. Add another 1/3 of the flour, then more milk and so on. Add finely ground nutmeg. Add 3 egg yolks and heat until right before the mixture sets (yeah &#8211; I admit &#8211; this is not very precise&#8230;). Then add the caviar. Beat egg whites stiff and fold them in. Pour into greased soufflé dish and bake at 220 °C for about 15 min. </p>
<p>Verdict: Aromas blend well together, but when eaten alone it&#8217;s perhaps a little bland. But I&#8217;m quite sure that it could be succesfully incorporated into a menu together with something acidic. The texture was nice, but the soufflé quickly falls together once it&#8217;s removed from the oven (I&#8217;ll have to post more on the chemistry of soufflés some other time &#8211; Hervé This has written a lot about this). </p>
<p>If you try to make this &#8211; note that white chocolate doesn&#8217;t behave excately like butter when you add the flour. It all got very thick, very fast &#8211; that&#8217;s why I started adding milk early. I also guess you have to be really careful when heating the whtie chocolate, but I didn&#8217;t do any stress tests here.</p>
<p><img src='http://blog.khymos.org/wp-content/2008/01/white-chocolate-caviar-1.jpg' alt='white-chocolate-caviar-1.jpg' /><br />
<em>This is what the mix looks like before I folded in the egg whites.</em></p>
<p>For my first attempt at this recipe I used 20 g flour and 15 g caviar. The result was that the caviar sedimented before the soufflé had set, besides the fact that one could hardly taste the caviar at all. On my second attempt however, there was enough flour to keep the caviar suspended until the soufflé set. And one could actually also taste the caviar.</p>
<p><img src='http://blog.khymos.org/wp-content/2008/01/white-chocolate-caviar-4.jpg' alt='white-chocolate-caviar-4.jpg' /></p>
<p><strong>And now on to the chemistry behind:</strong><br />
I promised that I would come back with more information about the chemistry behind this pairing, but there isn&#8217;t very much information out there. There is one paper on <a href="http://dx.doi.org/10.1016/S0308-8146(99)00171-5 ">aroma development in block-milk</a> which used in the production of white chocolate. This paper lists a couple of volatiles, but only with their relative peak areas. Turning to caviar (or roe), there is a recent paper on <a href="http://dx.doi.org/10.1021/jf049456g">flavor characterization of ripened cod roe</a>, and this paper includes qualitative information about odor intensity. </p>
<p>Comparing the list of volatiles, the following volatiles which contribute substantially to the odor of ripened cod roe are also found in block milk (followed by odor thresholds in water, given in ppb, taken from <a href="http://www.leffingwell.com/odorthre.htm">this page</a>):</p>
<p>2-butanone (50000 ppb)<br />
2-methylbutanal (1 ppb)<br />
3-methylbutanal (0.2-2 ppb)<br />
pentanal (na)</p>
<p>Of these, the first has a high odor threshold, so it&#8217;s not likely to be an impact odorant in block-milk (and white chocolate). The methylbutanals however probably contribute to the overlapping aroma of roe and white chocolate. I didn&#8217;t find any threshold value for pentanal.</p>
<p>One group of compounds which was not mentioned in the paper on cod roe odor from 2004, but which was mentioned in a Russian paper from 1967 are amines (Golovnya: &#8220;Gas-chromatographic analysis of amines in volatile substances of salmon caviar&#8221;). Considering the fact that trimethylamine has a threshold in the range of 0.37-1.06 ppb, and that trimethylamine is found in block-milk suggests that it might contribute significantly to the odor of both white chocolate and roe. I guess the reason trimethylamine (and the whole range of other, closely related amines) is not found in the odor analysis in the 2004 paper has to do with the analytical method used.</p>
<p>The fact that amines are crucial is further supported by the Guardian <a href="http://www.guardian.co.uk/weekend/story/0,,708669,00.html">article</a> I quoted from in the beginning where Heston Blumenthal describes how he turned to François Benzi, a flavor chemist at Firmenich, to find out why white chocolate and caviar is such a good match. Benzi concludes that it is due to the presence of similar amines in white chocolate and caviar.</p>
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		<title>Foodpairing website launched</title>
		<link>http://blog.khymos.org/2007/11/22/foodpairing-website-launched/</link>
		<comments>http://blog.khymos.org/2007/11/22/foodpairing-website-launched/#comments</comments>
		<pubDate>Wed, 21 Nov 2007 23:20:52 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[websites]]></category>
		<category><![CDATA[Bernard Lahousse]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/11/22/foodpairing-website-launched/</guid>
		<description><![CDATA[The long awaited website on foodpairings has now been launched, and they&#8217;ve also registred the corresponding blogspot name (which isn&#8217;t online yet as of today). The beautiful photos, great design and easy maneuvering makes it an excellent place to start if you are looking for some new and perhaps surprising combinations of foods. The foods [...]]]></description>
			<content:encoded><![CDATA[<p><a href="http://www.foodpairing.be/"><img src='http://blog.khymos.org/wp-content/2007/11/foodpairing.jpg' alt='foodpairing.jpg' /></a></p>
<p>The long awaited <a href="http://www.foodpairing.be/">website on foodpairings</a> has now been launched, and they&#8217;ve also registred the corresponding <a href="http://foodpairing.blogspot.com/">blogspot name</a> (which isn&#8217;t online yet as of today). The <strong>beautiful photos, great design and easy maneuvering</strong> makes it an excellent place to start if you are looking for some new and perhaps surprising combinations of foods. The foods are grouped into categories such as cocoa (?), dairy, fruits, meat, sea food and vegetables. One of the vegetables listed is cauliflower, and clicking it reveals that the topic of <a href="http://flavoralchemy.squarespace.com/journal/tgrwt-7-round-up.html">TGRWT #7</a> (caramelized cauliflower and cocoa) is one of several possible combinations. This is how it is displayed (an important detail is that the shorter the distance between the names, the more flavours they have in common):</p>
<p><a href="http://users.telenet.be/frozen.mini/foodpairing/cauliflower.htm"><img src='http://blog.khymos.org/wp-content/2007/11/foodpairing-cauliflower.jpg' alt='foodpairing-cauliflower.jpg' /></a><br />
<em>(click to open the full picture from the foodpairing.be site)</em></p>
<p>As an added bonus interchangeable herbs and spices are also listed. This is how it works:</p>
<blockquote><p>A food product has a specific flavour because of a combination of different flavours. Like basil taste like basil because of the combination of linalool, estragol, …. So if I want to reconstruct the basil flavour without using any basil, you have to search for a combination of other food products where one contains linalool (like coriander), one contains estragol (like tarragon),&#8230; So I can reconstruct basil by combining coriander, tarragon, cloves, laurel. The way to use it is to take from each branch of the plot one product and make a combination of those food products.
</p></blockquote>
<p>It should be noted that the proximity of the foods in the diagrams is based on the <em>number of volatile compounds</em> they have in common, <em>not the actual key odorants</em>. As I have elaborated on <a href="http://blog.khymos.org/2007/05/05/two-flavour-pairing-case-studies/">previously</a>, pairings like these should preferably be based on odor activity values (OAV). Or to put it differently, if the volatiles shared by two foods are not the ones that actually contribute to the overall flavor, there is no reason to expect that they go well together from a chemical perspective (which is not to say that they won&#8217;t match, only that if they do, it is for some other reason). This is a limitation both of the foodpairing site, but of course also of the food blogging event <a href="http://blog.khymos.org/category/tgrwt/">They Go Really Well Together</a> (or TGRWT) which I have initiated. Having said this, I still believe that the foodpairing site is an excellent place to start, especially if you like to improvise in the kitchen. I sincerely believe that the site will spark the creativity both of professional and amateur cooks (just like TGRWT already has)! I should add that the website is set up by the people behind <a href="http://www.foodfordesign.be/">Food for Design</a>, so no wonder it looks so good! </p>
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		<title>TGRWT #5: Chocolate and meat</title>
		<link>http://blog.khymos.org/2007/08/05/tgrwt-5-chocolate-and-meat/</link>
		<comments>http://blog.khymos.org/2007/08/05/tgrwt-5-chocolate-and-meat/#comments</comments>
		<pubDate>Sat, 04 Aug 2007 23:07:24 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/08/05/tgrwt-5-chocolate-and-meat/</guid>
		<description><![CDATA[Amrita of Le Petite Boulanger has announced the foods to pair for the fifth round: chocolate and meat! And in case you didn&#8217;t notice, Dennis has written an excellent summary of the mustard-mint recipes of round four. I was not able to figure out which odorants actually formed the basis for the mustard-mint pairing (and [...]]]></description>
			<content:encoded><![CDATA[<p><img src='http://blog.khymos.org/wp-content/2007/08/tgrwt-5.png' alt='tgrwt-5.png' /></p>
<p>Amrita of <a href="http://lepetiteboulanger.blogspot.com/2007/08/announcement-chocolate-and-meat-tgrwt-5.html">Le Petite Boulanger</a> has announced the foods to pair for the fifth round: chocolate and meat! And in case you didn&#8217;t notice, Dennis has written an excellent <a href="http://www.kookjegek.nl/archives/168">summary of the mustard-mint recipes</a> of round four.</p>
<p>I was not able to figure out which odorants actually formed the basis for the mustard-mint pairing (and perhaps there is none&#8230; as I&#8217;ve touched upon before, some of the data is hard to come at so it&#8217;s difficult to check all the entries of my <a href="http://khymos.org/pairings.php">compiled list</a>). At M&#8217;s blog however you can find more info on the <a href="http://blogger.xs4all.nl/wk9/archive/2007/07/05/255399.aspx">cold receptors</a> which are triggered by both mint and mustard.</p>
<p>Fortunately data for chocolate and meat is available: odor activity values for <a href="http://dx.doi.org/10.1021/jf060728k">cocoa</a> and flavour dilution values for <a href="http://dx.doi.org/10.1007/PL00005496">boiled beef</a> and <a href="http://dx.doi.org/10.1007/BF01193213">roasted beef</a>. All flavour compounds were ranked and compounds given the same color coding as <a href="http://blog.khymos.org/2007/05/05/two-flavour-pairing-case-studies/">before</a>. As you can see, there is considerable overlap between chocolate and meat.</p>
<p><a href='http://blog.khymos.org/wp-content/2007/08/chocolate-meat-pairing.png' title='chocolate-meat-pairing.png'><img src='http://blog.khymos.org/wp-content/2007/08/chocolate-meat-pairing.thumbnail.png' alt='chocolate-meat-pairing.png' /></a><br />
<em>(click to enlarge)</em></p>
<p>And here&#8217;s what the molecules that are found both in cocoa and beef look like. Notice that this pairing is dominated by furanones and pyrazines. The molecules are ranked according the the odor activity values in cocoa.</p>
<p><img src='http://blog.khymos.org/wp-content/2007/08/chocolate-meat-molecules.png' alt='chocolate-meat-molecules.png' /></p>
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		<title>TGRWT #3: Strawberries and coriander</title>
		<link>http://blog.khymos.org/2007/06/07/tgrwt-3-strawberries-and-coriander/</link>
		<comments>http://blog.khymos.org/2007/06/07/tgrwt-3-strawberries-and-coriander/#comments</comments>
		<pubDate>Thu, 07 Jun 2007 20:59:24 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[coriander]]></category>
		<category><![CDATA[Heston Blumenthal]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>
		<category><![CDATA[strawberries]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/06/07/tgrwt-3-strawberries-and-coriander/</guid>
		<description><![CDATA[It’s time for the third round of the They go really well together food blogging event (TGRWT #3). Ingredients to pair this time are strawberry and coriander (coriander sativum, also known as cilantro in North America). You can use fresh leaves, whole seeds or ground seeds &#8211; it&#8217;s all your choice. Deadline is July 1st, [...]]]></description>
			<content:encoded><![CDATA[<p><img src='http://blog.khymos.org/wp-content/2007/06/tgrwt-3.png' alt='tgrwt-3.png' /></p>
<p>It’s time for the third round of the <em>They go really well together</em> food blogging event (TGRWT #3). Ingredients to pair this time are <strong>strawberry and coriander</strong> (<em><a href="http://en.wikipedia.org/wiki/Coriander">coriander sativum</a></em>, also known as cilantro in North America). You can use fresh leaves, whole seeds or ground seeds &#8211; it&#8217;s all your choice. Deadline is July 1st, so there’s still a couple of weekends left for you to do some experimental cooking. This round is hosted by Evelin at <a href="http://bounteous-bites.blogspot.com/2007/06/tgrwt3-is-here.html">Bounteous bites</a>, so check out her post with instructions on how to participate! She will also post a round-up in due time. And in case you&#8217;ve missed it, Tara has posted the <a href="http://shouldyoueatthat.blogspot.com/2007/05/tgrwt2-round-up.html">round-up of TGRWT #2</a> featuring banana and parsley.</p>
<p>The first place I saw this combination mentioned at <a href="http://forums.egullet.org/index.php?showtopic=12012&#038;view=getlastpost">eGullet</a> in a post by Heston Blumenthal. Six impact odorants have been <a href="http://dx.doi.org/10.1021/jf960366o">identified</a> for strawberry juice: </p>
<blockquote><p>(Z)-3-hexenal (green)<br />
2,5-dimethyl-4-hydroxy-3(2H)-furanone (caramel-like, sweet)<br />
methyl butanoate (fruity)<br />
ethyl butanoate (fruity)<br />
methyl 2-methylpropanoate (fruity)<br />
2,3-butanedione (buttery)</p></blockquote>
<p>The paper &#8220;Character-impact aroma components of coriander (Coriandrum sativum) herb&#8221; by Cadwallader et al. (couldn&#8217;t find any link for this) presented at the 5th Chemical Congress of North America lists (Z)-3-hexenal (green/cut-grass) as an impact odorants based on AEDA (aroma extraction dilution analysis), so there is at least one overlap between the impact odorants of strawberry and coriander (shown below).  Please let me know if you should find odor activity values (OAV) for the volatile compounds in coriander. A search at The Good Scents Company also gives <a href="http://www.google.com/search?q=site%3Awww.thegoodscentscompany.com+strawberry+coriander">many hits for strawberry and coriander</a>.</p>
<p><img src='http://blog.khymos.org/wp-content/2007/06/z-3-hexenal.png' alt='z-3-hexenal.png' /></p>
<p>If you have a hard time finding inspiration for this round, how about <a href="http://www.hertzmann.com/articles/2001/fraises/recipes/recipe09.html">Mousses de fraises à la coriandre</a>, <a href="http://vanillagarlic.blogspot.com/2007/02/strawberry-cupcake-five-ways.html">Cupcake</a>, <a href="http://seattlepi.nwsource.com/food/315810_fresh16.html">Strawberry grapefruit dressing</a>, <a href="http://homecooking.about.com/od/condimentrecipes/r/blcon24.htm">Strawberry salsa</a> or <a href="http://www.answerpoint.org/columns2.asp?column_id=1194&#038;column_type=feature">Strawberry spring rolls</a>? </p>
<p>Good luck!</p>
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		<title>TGRWT #2: Banana and parsley</title>
		<link>http://blog.khymos.org/2007/05/08/tgrwt-2-banana-and-parsley/</link>
		<comments>http://blog.khymos.org/2007/05/08/tgrwt-2-banana-and-parsley/#comments</comments>
		<pubDate>Tue, 08 May 2007 21:32:32 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[TGRWT]]></category>
		<category><![CDATA[flavor pairing]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[banana]]></category>
		<category><![CDATA[Heston Blumenthal]]></category>
		<category><![CDATA[impact odorants]]></category>
		<category><![CDATA[OAV]]></category>
		<category><![CDATA[odor activity value]]></category>
		<category><![CDATA[parsley]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/2007/05/08/tgrwt-2-banana-and-parsley/</guid>
		<description><![CDATA[It&#8217;s time for the second round of the They go really well together food blogging event (hereafter referred to as TGRWT #2). Ingredients to pair this time are banana and parsley, which should be an easy match compared to last round with coffee, chocolate and garlic. Deadline is June 1st, so there&#8217;s still a couple [...]]]></description>
			<content:encoded><![CDATA[<p>It&#8217;s time for the second round of the <em>They go really well together</em> food blogging event (hereafter referred to as TGRWT #2). Ingredients to pair this time are banana and parsley, which should be an easy match compared to <a href="http://blog.khymos.org/2007/05/02/tgrwt-1-roundup-coffee-chocolate-garlic/">last round </a>with coffee, chocolate and garlic. Deadline is June 1st, so there&#8217;s still a couple of weekends left for you to do some experimental cooking. The event and round-up is hosted by Tara over at <a href="http://shouldyoueatthat.blogspot.com/">Should you eat that</a>, so check out her post with <a href="http://shouldyoueatthat.blogspot.com/2007/05/announcing-tgrwt-2.html">instructions</a> on how to participate!</p>
<p><img src='http://blog.khymos.org/wp-content/2007/05/tgrwt-2.jpg' alt='tgrwt-2.jpg' /></p>
<p>I&#8217;ve tried to track down the origin of this pairing. First place I saw it mentioned was by Heston Blumenthal at <a href="http://forums.egullet.org/index.php?showtopic=12012&#038;view=getlastpost">eGullet</a>, and in an <a href="http://enjoyment.independent.co.uk/food_and_drink/features/article622637.ece">interview</a> with The Independent Heston explains how he discovered it:</p>
<blockquote><p>He gives an example of this creative process in action. &#8220;I was cooking rabbit stew for the kids last summer in France, lifted the lid and threw in chopped parsley and got a smell of banana.&#8221; Which prompted him to pair banana with parsley, and banana with tarragon. &#8220;It worked really well.&#8221;</p></blockquote>
<p>I have found odour activity values (OAV) for <a href="http://www3.interscience.wiley.com/cgi-bin/abstract/10005836">parsley</a>, but not for banana. A <a href="http://www.google.com/search?q=parsley+banana+site%3Athegoodscentscompany.com">search</a> at The good scents company reavels that (Z)-3-hexen-1-yl formate and linalool are present in both banana and parsley. When comparing the OAV data of parsley with a search for banana only at The good scents company oct-1-en-3-one and (Z)-hex-3-enyl acetate were also found. Please post a comment if you have more data on the volatile compounds of this pairing and their OAV values.</p>
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