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	<title>Khymos &#187; yeast</title>
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	<link>http://blog.khymos.org</link>
	<description>- dedicated to molecular gastronomy</description>
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		<title>No-knead bread</title>
		<link>http://blog.khymos.org/2010/12/22/no-knead-bread/</link>
		<comments>http://blog.khymos.org/2010/12/22/no-knead-bread/#comments</comments>
		<pubDate>Tue, 21 Dec 2010 23:12:50 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[equipment]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[news articles]]></category>
		<category><![CDATA[recipe]]></category>
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		<category><![CDATA[Baker's percentage]]></category>
		<category><![CDATA[baker's yeast]]></category>
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		<category><![CDATA[bread]]></category>
		<category><![CDATA[cast iron]]></category>
		<category><![CDATA[Dutch oven]]></category>
		<category><![CDATA[flour]]></category>
		<category><![CDATA[hydration]]></category>
		<category><![CDATA[Jim Lahey]]></category>
		<category><![CDATA[no-knead]]></category>
		<category><![CDATA[Saccharomyces cerevisiae]]></category>
		<category><![CDATA[volume measurement]]></category>
		<category><![CDATA[weight measurement]]></category>
		<category><![CDATA[yeast]]></category>
		<category><![CDATA[yeast viability]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=526</guid>
		<description><![CDATA[Update: I&#8217;ve written up a short post about no-knead bread in Norwegian &#8211; Brød uten å kna &#8211; to accompany my appearance in the popular science program Schrödingers katt. I know &#8211; since the NY Times article about Jim Lahey in 2006 the no-knead breads have been all over the internet, newspapers and now even [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2010/12/no-knead-1.jpg" alt="" title="no-knead-1" width="620" height="620" class="alignnone size-full wp-image-2595" /></p>
<p><strong>Update:</strong> <em>I&#8217;ve written up a short post about no-knead bread in Norwegian &#8211; <a href="http://blog.khymos.org/norsk/brød-uten-a-kna/">Brød uten å kna</a> &#8211; to accompany my <a href="http://www.nrk.no/nett-tv/klipp/710718/">appearance</a> in the popular science program Schrödingers katt.</em></p>
<p>I know &#8211; since the <a href="http://www.nytimes.com/2006/11/08/dining/08mini.html">NY Times article about Jim Lahey in 2006</a> the no-knead breads have been all over the internet, newspapers and now even appear in <a href="http://www.amazon.com/exec/obidos/ASIN/0393066304/kjemiihverdao-20">numerous</a> <a href="http://www.amazon.com/exec/obidos/ASIN/1580089984/kjemiihverdao-20">books</a> &#8211; this is really old news. But the no-knead breads are really tasty as well, so I hope you&#8217;ll forgive me! When I give popular science talks about chemistry in the kitchen the one thing I&#8217;m always asked about is the no-knead recipe I show, so I thought it was about time to publish a recipe. Surely, everyone can google it &#8211; but regrettably many (if not most?) recipes are given in non-metric, volume based units &#8211; even Jim Lahey&#8217;s original recipe. And for baking this is really a drawback because the density of flour depends so much on how tight you pack it. Oh yeah, and I will also try to <strong>explain why and how</strong> the no-knead bread works.<br />
<span id="more-526"></span><br />
The stretchy <a href="http://en.wikipedia.org/wiki/Gluten">gluten</a> which gives a dough its elasticity is formed when the two proteins <a href="http://en.wikipedia.org/wiki/Glutenin">glutenin</a> and <a href="http://en.wikipedia.org/wiki/Gliadin">gliadin</a> bind together. Kneading can speed up this process, but in a wetter dough <strong>the mobility of glutenin and gliadin increases</strong>, and given enough time they can actually manage it all by themselves. That&#8217;s why a wet dough needs time to develop the gluten network, but no kneading. </p>
<p><img src="http://blog.khymos.org/wp-content/2010/12/no-knead-2-yeast.jpg" alt="" title="no-knead-2-yeast" width="620" height="620" class="alignnone size-full wp-image-2594" /><br />
<em>This is to show what 3 g fresh yeast looks like, in case you don&#8217;t have a balance that can accurately weigh such a small mass.</em></p>
<p>I&#8217;ve often seen it mentioned that a longer fermentation and/or less yeast gives a richer aroma. I think it&#8217;s true, but I&#8217;m not quite sure why this is the case. If the flavor compounds are produced proportionally to the carbon dioxide, the easiest way to increase flavor would be to up the amount of yeast. A lower temperature and/or less yeast would only mean that it takes longer to produce the same amount of carbon dioxid and flavor compounds. However, most of the advice I&#8217;ve seen about baking suggests that there is a flavor improvement by extending the fermentation time. So to rephrase the question: <strong>Why is the desirable bread flavor not proportional to the amount of yeast added?</strong> Some claim that the bitter flavor of pure yeast can dominate the flavor of the resulting bread if used at to high levels &#8211; but I have never been bothered by yeast flavor, even when using 50 g of fresh yeast for 1-2 kg of flour. But maybe I&#8217;m just insensitive to this bitterness? It could also be that the flavor profile produced by the yeast benefits from the lower temperature, but I doubt that one would actually be able to tell the difference in bread (you can easily tell the difference in beer, but here the fermentation may take from days to weeks &#8211; see also my post on <a href="http://blog.khymos.org/2010/09/06/baking-with-hefeweizen-yeast/">Baking with hefeweizen yeast</a>). Another possible explanation could be that <strong>enzymes</strong>, which are present in the flour or slowly produced by the yeast, contribute significantly to the flavor if given enough time. <a href="http://en.wikipedia.org/wiki/Amylase">Amylase</a> is one such enzyme which converts starch to sugar. It&#8217;s naturally produced by yeast, but it&#8217;s often added in pure form to &#8220;industrial doughs&#8221; to speed things up. Yet another explanation is that a long proofing time will allow a certain production of organic acids by the <strong>bacteria</strong> which are always present (this of course is what gives sour doughs their characteristic flavor).</p>
<p>The most unusual step in making no-knead bread is that it&#8217;s baked in a preheated heavy cooking pan, also known as a Dutch oven, usually made from cast iron. But this is indeed very clever! Professional bakers are lucky to have steam inlets in their ovens, because <strong>steam has a heat capacity which is much higher than that of dry air</strong>. Because of this the loaf will heat up quicker, giving a better oven spring. But the moist air inside the covered pan does more: as long as the loaf is colder than the pan the moisture will actually condense on the surface of the bread, thereby keeping it moist. This ensures that the oven spring is not hindered by a dry crust. Secondly, this moisture is important for a proper gelatinization of the starch: we are setting the stage for the Maillard reaction.</p>
<p>After about 30 min the lid is removed. At this point one will see the nice oven spring, but also notice that no browning has occured sine the temperature in the crust has been kept below the boiling point due the condensation of moisture on the surface. <strong>Once the lid is removed moisture can escape and the temperature in the crust rapidly rises above 110 °C where the Maillard reaction proceeds more rapidly.</strong> This is what gives the crust it&#8217;s nice brown color and also gives rise to the beautiful smell of fresh baked bread. At this point, the total baking time should be determined by the color of the loaf. When the surface is sufficiently browned your no-knead bread is finished. </p>
<p>Salt is very important, so don&#8217;t omit it from the bread. If you try to reduce the amount of salt in your diet &#8211; do so by eating less fast food and industrially prepared food. Don&#8217;t mess with the salt levels of home baked bread. It&#8217;s there for the taste, but it also improves the strength of the gluten network. </p>
<p><img src="http://blog.khymos.org/wp-content/2010/12/no-knead-3-front.jpg" alt="" title="no-knead-3-front" width="620" height="246" class="alignnone size-full wp-image-2593" /></p>
<p><strong>No-knead bread</strong> (based on Jim Lahey&#8217;s recipe)</p>
<p>390 g all purpose white flour<br />
300 g water (77%)<br />
7 g salt (1.8%)<br />
~1-3 g fresh yeast </p>
<p>Mix everything until the flour is completely moistened. Cover and leave for 15-25 hours. Pour onto a floured surface, fold 3-4 times, shape rapidly into a boule, place it on a generously floured cloth/towel seamside down and proof until doubled in size (~2 hours). Dump seam side up into a cast iron pan preheated to 230 °C and bake with the lid on for 30 min. Take the lid of and bake until the crust has a dark golden color &#8211; approximately 15 min.</p>
<p><img src="http://blog.khymos.org/wp-content/2010/12/no-knead-6-proofing.jpg" alt="" title="no-knead-6-proofing" width="620" height="620" class="alignnone size-full wp-image-2607" /><br />
<em>Proofing the loaf on well floured towel</em></p>
<p>The percentages in the recipe are so-called Baker&#8217;s percentages, giving the amount of the ingredients in percent of the flour. The amount of water is often referred to as the degree of hydration. I&#8217;ve had good results with a hydration of 77%, but you may want to adjust this depending on your preferences. In fact, <strong>it&#8217;s impossible to know exactly what hydration Jim Lahey used because of his volume measurements</strong>! The <a href="http://www.sullivanstreetbakery.com/recipe/baking-perfect-loaf-bread-home">recipe</a> posted on the Sullivan Street Bakery&#8217;s homepage has a hydration of 80%, but I wonder whether the amounts are calculated or measured. My advice is to start at 77% and then adjust up/down in the range 75-80%. By adjusting the hydration you will indirectly also adjust the size of the pores (more water = larger pores) and the moistness of the bread. The higher hydration will of course yield a more sticky dough, but don&#8217;t forget that it&#8217;s a no-knead bread, so you&#8217;re supposed to handle the dough as little as possible.</p>
<p>Regarding the amount of yeast I&#8217;d start with 3 g, but if you feel that it rises to quickly you can lower this to 1-2 g. The main reason for this variability is that the activity (= number of living yeast cells) of fresh yeast decreases with time. Homebrewers can <a href="http://www.mrmalty.com/calc/calc.html">calculate exact pitching rates for yeast</a> based on a ~5% loss of viability per week for liquid yeast. My guess is that compressed yeast is more stable, but I haven&#8217;t been able to find any data on it&#8217;s viability. </p>
<p><img src="http://blog.khymos.org/wp-content/2010/12/no-knead-4-top.jpg" alt="" title="no-knead-4-top" width="620" height="310" class="alignnone size-full wp-image-2592" /><br />
<em>My no-knead breads look a bit different every time I bake them, but that&#8217;s OK.</em></p>
<p>The required hydration depends a lot on flour as well of course! No-knead breads can greatly benefit from substituting some of the white flour with whole grain flours, or ancient cereals such as emmer (farro), spelt, einkorn etc. Whole grain flours tend to bind more water though and develop a less strong gluten network. This last point is well illustrated by my failed attempt to bake a no-knead bread with 100% emmer. The resulting flat loaf is shown in the picture below.</p>
<p><img src="http://blog.khymos.org/wp-content/2010/12/no-knead-5-emmer.jpg" alt="" title="no-knead-5-emmer" width="620" height="307" class="alignnone size-full wp-image-2591" /><br />
<em>No-knead bread with 100% emmer did not have a sufficiently strong gluten network &#8211; the bread ended up very flat&#8230;</em></p>
<p>Further reading:<br />
<a href="http://www.nytimes.com/2006/11/08/dining/08mini.html">The Secret of Great Bread: Let Time Do the Work</a> (original NY Times article)<br />
<a href="http://www.nytimes.com/2006/11/08/dining/081mrex.html?ref=dining">No-Knead Bread</a> (original recipe from Jim Lahey)<br />
<a href="http://www.nytimes.com/2007/11/21/dining/21brea.html">Soon the bread will be making itself </a><br />
<a href="http://www.nytimes.com/2007/11/21/dining/211brex.html?ref=dining">Simple Crusty Bread</a> (recipe)<br />
<a href="http://www.nytimes.com/2008/10/08/dining/08mini.html?_r=1&#038;ref=dining&#038;oref=slogin">No-Knead Bread: Not Making Itself Yet, but a Lot Quicker</a><br />
<a href="http://www.nytimes.com/2008/10/08/dining/081mrex.html?ref=dining">Speedy No-Knead Bread</a> (recipe)<br />
<a href="http://www.nytimes.com/2008/10/08/dining/082mrex.html?ref=dining">Fast No-Knead Whole Wheat Bread</a> (recipe)<br />
<a href="http://forums.egullet.org/index.php?/topic/95345-minimalist-no-knead-bread-technique/">eGullet thread on no-knead breads</a></p>
<img src="http://blog.khymos.org/?ak_action=api_record_view&id=526&type=feed" alt="" />]]></content:encoded>
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		<item>
		<title>Baking with hefeweizen yeast</title>
		<link>http://blog.khymos.org/2010/09/06/baking-with-hefeweizen-yeast/</link>
		<comments>http://blog.khymos.org/2010/09/06/baking-with-hefeweizen-yeast/#comments</comments>
		<pubDate>Mon, 06 Sep 2010 21:27:27 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[experiments]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[science]]></category>
		<category><![CDATA[baker's yeast]]></category>
		<category><![CDATA[baking]]></category>
		<category><![CDATA[baking stone]]></category>
		<category><![CDATA[beer]]></category>
		<category><![CDATA[beer yeast]]></category>
		<category><![CDATA[bread]]></category>
		<category><![CDATA[emmer]]></category>
		<category><![CDATA[farro]]></category>
		<category><![CDATA[hefeweizen]]></category>
		<category><![CDATA[Saccharomyces carlsbergensis]]></category>
		<category><![CDATA[Saccharomyces cerevisiae]]></category>
		<category><![CDATA[steam oven]]></category>
		<category><![CDATA[weizen]]></category>
		<category><![CDATA[wit]]></category>
		<category><![CDATA[yeast]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=2480</guid>
		<description><![CDATA[Wheat beers such as hefeweizen, weissbier and wit are all light beers made from a mix of malted barley and wheat. In southern Germany the typical hefeweizen is fermented with a non-flocculating yeast, and it is not filtered before bottling. This gives the beer a yeasty, bread like flavor accompanied by aromas reminiscent of banan, [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2010/09/hefeweizen_poolish.jpg" alt="" title="hefeweizen_poolish" width="620" height="620" class="alignnone size-full wp-image-2519" /></p>
<p>Wheat beers such as hefeweizen, weissbier and wit are all light beers made from a mix of malted barley and wheat. In southern Germany the typical hefeweizen is fermented with a non-flocculating yeast, and it is not filtered before bottling. This gives the beer a yeasty, bread like flavor accompanied by aromas reminiscent of banan, cloves (we&#8217;ve encountered that <a href="http://blog.khymos.org/2008/11/02/tgrwt-11-round-up/">combo before</a>), coriander and citrus. I&#8217;ve just begun to <a href="http://www.amazon.com/exec/obidos/ASIN/082472657X/kjemiihverdao-20">read</a> <a href="http://www.amazon.com/exec/obidos/ASIN/0937381888/kjemiihverdao-20">up</a> <a href="http://www.amazon.com/exec/obidos/ASIN/0195305426/kjemiihverdao-20">on</a> <a href="http://www.amazon.com/exec/obidos/ASIN/0470230622/kjemiihverdao-20">brewing</a> and my first batch of a partial mash hefeweizen is bubling along. <strong>As I pitched the liquid hefeweizen yeast into the wort I decided to keep a tiny amount for baking.</strong> If hefeweizen beer is reminiscent of bread, why not use the yeast for making bread? In particular I was curious whether some of the aroma top notes characterizing hefeweizen beer would stand out in bread made using the same yeast.<br />
<span id="more-2480"></span><br />
The specific yeast I used was obtained as a liquid suspension from <a href="http://www.whitelabs.com/index.html">White labs</a>. Their hefeweizen yeast strain (catalogue number WLP300) is <a href="http://www.mrmalty.com/yeast.htm">identical</a> to Weihenstephan 68. And in case you didn&#8217;t know &#8211; <a href="http://www.brauerei-weihenstephan.de/">Weihenstephan</a> is the world&#8217;s oldest brewery. Wine yeast is the same as beer yeast (or ale yeast to be more precise) and <a href="http://en.wikipedia.org/wiki/Baker's_yeast">baker&#8217;s yeast</a> &#8211; and they are all known under the latin name <em><a href="http://en.wikipedia.org/wiki/Saccharomyces_cerevisiae">Saccharomyces cerevisiae</a></em> (which literally translates to something like a &#8220;beer producing sugar munching fungi&#8221;). Why bother if they are all the same yeast you may ask. It&#8217;s a good question, but despite the common name they are different isolates with very different properties. They certainly have a lot in common: in the presence of air they consume sugars to grow, and in a closed environment without access to air the consumed sugars are instead converted to alcohol and carbon dioxide. <strong>But besides this main reaction there are hosts of other enzymes present that produce higher alcohols, aldehyes, acids, esters &#8211; all of them volatiles compounds that contribute significantly to flavor.</strong> And this is typically where the isolates of <em>S. cerevisia</em> differ. There&#8217;s a mind boggling array of beer yeasts available. Take a look at the yeast catalogues of <a href="http://www.whitelabs.com/beer/homebrew_strains.html">White labs</a>, <a href="http://www.wyeastlab.com/hb_products.cfm">Wyeast</a> or <a href="http://www.fermentis.com/FO/60-Beer/60-11_product_rangeHB.asp">Fermentis</a> to get an idea of the many yeast strains that are available (note that the lists includes both ale yeasts <em>S. cerevisia</em> which are top fermenting and lager yeasts <em>S. carlsbergensis</em> which are bottom fermenting, meaning that the yeast sinks to the bottom when the job is done). And if this doesn&#8217;t impress you &#8211; consider the fact that there are thousands of <em>S. cerevisia</em> isolates available from <a href="http://en.wikipedia.org/wiki/World_Federation_for_Culture_Collections">culture collections</a> around the world (<a href="http://www.atcc.org/">ATCC</a> and <a href="http://www.cbs.knaw.nl/databases/">CBS</a> are among the largest &#8211; do a search for <em>S. cerevisiae</em> at ATCC and it tells you to narrow your search because there are more than 5000 hits!). </p>
<p><img src="http://blog.khymos.org/wp-content/2010/09/hefeweizen_bread_slice.jpg" alt="" title="hefeweizen_bread_slice" width="620" height="620" class="alignnone size-full wp-image-2516" /></p>
<p>Apart from the specific strain used the <strong>fermentation conditions will also greatly influence the volatile profile</strong>: temperature, time, pH, micro and macro nutrients present, and the sugars available all have their say. A general advice for artisan breads is to use only a small amount of yeast (2-3 g) to start with and give the dough plenty of time to develop and rise. This gives a richer flavor compared to using 50 g of fresh yeast to obtain a rapid rise. Since I only started with about a 1/4 teaspoon of yeast slurry I first had to let the yeast grow and multiply. Since <em>S. cerevisiae</em> needs oxygen to grow I added 50 g of water to the yeast slurry and then <strong>used a hand mixer to whip in air</strong> for a minute or so before adding 50 g of flour. I left the <a href="http://en.wikipedia.org/wiki/Poolish">pre-ferment</a> (aka poolish or biga) on the benchtop and the next day there was plenty of bubbling activity. I added more water, whipped in more air with a hand mixer and once again added as much flour as water. This yielded an active starter and all was set for baking.</p>
<p><strong>Hefeweizen bread</strong></p>
<p><em>Pre-ferment (evening before baking day):</em><br />
65 g starter (100% hydration)<br />
110 g water<br />
110 g all purpose wheat flour</p>
<p><em>Baking day:</em><br />
285 g starter (100%) from day before<br />
466 g water<br />
250 g <a href="http://en.wikipedia.org/wiki/Emmer">emmer</a><br />
485 g all purpose wheat flour<br />
12 g salt</p>
<p>Total dough weight: 1498 g<br />
Hydration: 69%</p>
<p>Add water to starter and incorporate air with a hand mixer to give the yeast a good start. Mix in the flour, cover and leave at room temperature. Next day, mix all ingredients and leave to rise (this may take 1-3 hours). Divide in two, fold over repeatedly and shape into boules. Leave to rise. Preheat oven to 250 °C. Use a baking stone, and generate some steam in the oven during the first 10 min (see picture below). After 10 min, turn down to 220 °C and bake until crust has a nice golden crust.</p>
<p><img src="http://blog.khymos.org/wp-content/2010/09/steam_generation.jpg" alt="" title="steam_generation" width="620" height="620" class="alignnone size-full wp-image-2522" /><br />
<em>My current steam setup: I use ice cubes since this prevents a sudden gush of steam towards my hands. The stones serve as a heat reservoir ensuring that the ice cubes melt and evaporate within a couple of minutes. To cope with the heat shock I use a plate of stainless steel to hold the stones. After 10 min I open the oven door to vent out steam and remove the plate with the stones to allow an even heating (no reflection!) of the baking stone from below.</em></p>
<p>So how did it taste? The bread tasted excellent, but to be honest &#8211; <strong>I couldn&#8217;t detect any aroma that I can&#8217;t get using conventional baker&#8217;s yeast</strong>. The reason for this is probably that other flavors (i.e. from the flour, the baking process etc.) dominate. Another factor is that bread is only fermented for a couple of hours compared to several days for beer. This simply doesn&#8217;t give enough time for significant concentrations of the volatile compounds to develop. Lastly, the baking process will drive off the most volatile compounds. Nevertheless, I would still encourage you to try this! I didn&#8217;t get the result I hoped for (I was a little optimistic), but it&#8217;s a fun experiment to do, especially if you have some yeast left over from beer brewing anyway. </p>
<p><img src="http://blog.khymos.org/wp-content/2010/09/hefeweizen_bread.jpg" alt="" title="hefeweizen_bread" width="620" height="620" class="alignnone size-full wp-image-2517" /></p>
<p>I am by <a href="http://ryanbrews.blogspot.com/2009/05/bread-with-hefeweizen-beer-yeast.html">no</a> <a href="http://ryanbrews.blogspot.com/2009/05/bread-with-hefeweizen-beer-yeast-update.html">means</a> <a href="http://www.thefreshloaf.com/node/6772/beer-yeast">the</a> <a href="http://chowhound.chow.com/topics/618118">first</a> to try this. But it seems that results are mixed. Some complain about slow rising doughs. But there are also many misconceptions around. One is that some yeasts produce more alcohol whereas other yeasts produce more gas. As long as we&#8217;re talking about anaerobic fermentation of sugar to ethanol and carbon dioxide this is plain wrong as ethanol and carbon dioxide are produced in a 1:1 ratio. There is also some confusion with regards to the naming (i.e. beer yeast, ale yeast, brewer&#8217;s yeast, baker&#8217;s yeast etc. &#8211; when all in fact are the same yeast).</p>
<p><img src="http://blog.khymos.org/wp-content/2010/09/hefeweizen_bread_crumb.jpg" alt="" title="hefeweizen_bread_crumb" width="620" height="620" class="alignnone size-full wp-image-2518" /></p>
<p>Since the bread came out just like bread made with conventional baker&#8217;s yeast it&#8217;s fair to turn the question around: Do the different beer yeasts really make a difference? I did a quick search in the scientific littereature and found a couple of papers that study the effect of yeast strains on the formation of volatile compounds in beer and wine:</p>
<p><a href="http://dx.doi.org/10.1021/jf9807317">Yeast Influence on Volatile Composition of Wines</a><br />
<a href="http://www.ajevonline.org/cgi/content/abstract/33/2/94">Ester Concentration Differences in Wine Fermented by Various Species and Strains of Yeasts</a><br />
<a href="http://dx.doi.org/10.1002/jsfa.2740620213">Synthesis of volatile phenols by Saccharomyces cerevisiae in wines</a><br />
<a href="http://dx.doi.org/10.1016/S0168-1605(03)00290-3">Function of yeast species and strains in wine flavour</a><br />
<a href="http://dx.doi.org/10.1128/AEM.69.9.5228-5237.2003">Expression Levels of the Yeast Alcohol Acetyltransferase Genes ATF1, Lg-ATF1, and ATF2 Control the Formation of a Broad Range of Volatile Esters</a></p>
<p>I haven&#8217;t had the opportunity to dig really into this, but from the abstracts it definitely seems to be the case that the selection of yeast strains also play a vital role in the resulting aroma profile of the beer.</p>
<p>Oh yeah, one more thing: For this particular bread I used <a href="http://en.wikipedia.org/wiki/Emmer">emmer</a> from a local mill, <a href="http://www.holli-molle.no/">Holli Mølle</a>, specializing in ancient cereals. Emmer (aka farro) doesn&#8217;t form as much gluten as conventional wheat (I tried making a 100% emmer no-knead bread which tasted nice but was a fiasco shape wise&#8230;), but it does lend a light greyish/brown color to the crumb and also gives the bread a richer flavor. But the use of emmer is of course not a pre-requisite if you want to bake with beer yeast <img src='http://blog.khymos.org/wp-includes/images/smilies/icon_smile.gif' alt=':)' class='wp-smiley' /> </p>
<p><img src="http://blog.khymos.org/wp-content/2010/09/emmer_holli.jpg" alt="" title="emmer_holli" width="620" height="620" class="alignnone size-full wp-image-2523" /><br />
<em><a href="http://www.norskdesign.no/emballasjedesign/holli-moelle-oekologisk-steinmalt-mel-article7687-610.html">Looks good</a> and tastes good!</em></p>
<img src="http://blog.khymos.org/?ak_action=api_record_view&id=2480&type=feed" alt="" />]]></content:encoded>
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		<title>Sourdough work in progress (part II)</title>
		<link>http://blog.khymos.org/2009/10/18/sourdough-work-in-progress-part-ii/</link>
		<comments>http://blog.khymos.org/2009/10/18/sourdough-work-in-progress-part-ii/#comments</comments>
		<pubDate>Sun, 18 Oct 2009 21:32:28 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[academic articles]]></category>
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		<category><![CDATA[science]]></category>
		<category><![CDATA[acetic acid]]></category>
		<category><![CDATA[aeration]]></category>
		<category><![CDATA[Baker's percentage]]></category>
		<category><![CDATA[hydration]]></category>
		<category><![CDATA[LAB]]></category>
		<category><![CDATA[lactic acid]]></category>
		<category><![CDATA[lactic acid bacteria]]></category>
		<category><![CDATA[lactobacillus]]></category>
		<category><![CDATA[pH]]></category>
		<category><![CDATA[Saccharomyces exiguus]]></category>
		<category><![CDATA[sourdough]]></category>
		<category><![CDATA[sourdough starter]]></category>
		<category><![CDATA[yeast]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=1650</guid>
		<description><![CDATA[A sourd dough bread made from a spontaneous starter After 7 days of feeding my sour dough starter &#8220;took off&#8221; and was ready for baking. Even with a water bath set to 28 °C it took longer than expected. I started off with 100% hydration as this is convenient when you have to feed your [...]]]></description>
			<content:encoded><![CDATA[<p><a href="http://blog.khymos.org/wp-content/2009/09/sd-bread-1.jpg"><img src="http://blog.khymos.org/wp-content/2009/09/sd-bread-1.jpg" alt="sd-bread-1" title="sd-bread-1" width="620" height="620" class="alignright size-full wp-image-1792" /></a><br />
<em>A sourd dough bread made from a spontaneous starter</em></p>
<p>After 7 days of feeding my sour dough starter &#8220;took off&#8221; and was ready for baking. Even with a water bath set to 28 °C it took longer than expected. <a href="http://blog.khymos.org/wp-content/2009/10/yeast_kinetics.png"><img src="http://blog.khymos.org/wp-content/2009/10/yeast_kinetics.png" alt="yeast_kinetics" title="yeast_kinetics" width="300" height="196" class="alignright size-full wp-image-1843" /></a> I started off with 100% hydration as this is convenient when you have to feed your starter frequently. Using only whole grain rye flour and water, I fed my starter every 12 hours (I&#8217;ve included details of the &#8220;feeding schedule&#8221; at the end of this post). This time interval is based on the growth cycle of yeast, where the yeast after an exponential growth phase reaches a plateau after 8-12 hours. This is the best time for feeding the starter.</p>
<p>There seems to be a consensus that a wet starter <span id="more-1650"></span>(i.e. 100% <a href="http://en.wikipedia.org/wiki/Bakers_percentage">hydration</a>) favors growth of lactic acid bacteria (LAB) which in turn produce acids. The low pH after 2 days in my starter suggests plenty of LAB activity, so the main challenge for me was to get the yeast growing. Considering the fact that the yeasts found in sourdoughs prefer areob conditions for growth, I should have whisked in more air with each addition of water. <strong>And I wonder if this is the origin of the widespread myth that you &#8220;catch wild yeasts from the air&#8221;.</strong> I&#8217;m quite sure whisking helps, but what you do is not to catch yeast, but rather feed oxygen to your starter. This needs testing though! Most starter recipes call for discarding of half or even more of the starter before each feeding. Even though it seems wasteful <strong>I wonder if an important effect of this is to dilute the acid produced by the LAB</strong> (the flour may also act as a <a href="http://en.wikipedia.org/wiki/Buffering_agent">buffer</a>). This acid will to some extent slow the growth of yeasts (even though the sourdough yeasts are far more acid tolerant than the conventional brewer/baker&#8217;s yeast Saccharomyces cerevisia).</p>
<p><a href="http://blog.khymos.org/wp-content/2009/09/sd-starter.jpg"><img src="http://blog.khymos.org/wp-content/2009/09/sd-starter.jpg" alt="sd-starter" title="sd-starter" width="620" height="620" class="alignright size-full wp-image-1795" /></a><br />
<em>Bubbles indicating that the starter is active</em></p>
<p>Regarding temperature the growth optimum for LAB lies around 32-33 °C whereas the growth optimum for yeast is somewhat lower at 28 °C. The <a href="http://www.nyx.net/~dgreenw/sourdoughqa.html">sourdough FAQ</a> has further temperature recommendations which are illustarted in the graph below (data from <a href="http://www.nyx.net/~dgreenw/whatfactorsaffectmicrobial.html ">sourdough FAQ</a>). Holding this together with the notion (see for instance p. 272 in <a href="http://www.amazon.com/exec/obidos/ASIN/0824742648/kjemiihverdao-20">&#8220;The handbook of dough fermentations&#8221;</a>) that lower temperatures (20-25 °C) favor acetic acid production (= stronger flavor) and higher temperature (> 32 °C) favors lactic acid production (= milder flavor) it immediately becomes clear why a starter kept at roomtemperature has little yeast activity and smells of acetic acid. <strong>It need not be ruined, but is desperately in need of dilution, aeration and higher temperature.</strong></p>
<p><a href="http://blog.khymos.org/wp-content/2009/10/yeast_LAB_growth_rate_temperature.png"><img src="http://blog.khymos.org/wp-content/2009/10/yeast_LAB_growth_rate_temperature.png" alt="yeast_LAB_growth_rate_temperature" title="yeast_LAB_growth_rate_temperature" width="620" height="428" class="alignnone size-full wp-image-1848" /></a><br />
<em>Effect of temperature on growth of lactic acid bacteria and yeast based on data for optimum growth and no growth from the sourdough <a href="http://www.nyx.net/~dgreenw/whatfactorsaffectmicrobial.html">FAQ</a></em></p>
<p>I&#8217;ve kept the starter alive since August and baked with it at least once a week. I make sure that I keep 50-100 g which I store in the fridge. I&#8217;ve also frozen a sample just in case. I&#8217;ve changed from 100% hydration to 67% hydration, as this simplifies the calculations a little. On the evening before baking day I feed the starter to a total starter weight of approximately 900 g. The next day I bake bread as follows (the exact numbers were calculated using an internet <a href="http://samartha.net/SD/SDcalc04.html">sour dough calculator</a> with the following input: 3200 g total dough weight, 25% starter, 67% hydration of starter and final dough and 1.8% salt): </p>
<p><strong>Sour dough bread</strong><br />
949 g water<br />
1417 g flour *<br />
800 g starter (67% hydration, 25% of total dough)<br />
34 g salt</p>
<p>* for instance 300 g rye whole grain, 200 g rye fine, 300 g whole grain wheat and then plain all-purpose wheat flour up to 1417 g.</p>
<p>Mix water and flour mixed until all flour is wetted. Leave for 15-20 minutes (during which the <a href="http://en.wikipedia.org/wiki/Proofing_(baking_technique)#Dough_Processes">autolyse</a> proceeds &#8211; this eases subsequent mixing). Mix (see more comments below regarding method/machine for this) until dough is smooth, and while mixer is running add sour dough starter. Once the starter has been properly incorporated into the dough, add the salt. Cover and leave to rise until volume has increased 30-100% (I know &#8211; this is not very accurate&#8230;). I have left it in on my bench top, but while this worked well on warm August days, it seems to be less than ideal on colder October days. Leaving the dough to rise on top of the fridge might be a conventient compromise here as my current waterbath is not large enough to hold the mixing bowl with dough. <strong>The reason I use a starter with a 67% hydration is that I can be more sloppy when adding the starter to the sourdough as it will not change the hydration of the dough.</strong> After proofing and slashing I bake the breads on a baking stone which is preheated to 250 °C. Right beneath the baking stone I have a small oven proof dish that I fill with boiling water. This helps to moisten the air in the oven and it simulates the steam injection port of professional baking ovens. There are several reasons why this is important. Moist air is a better heat conductor than dry air, and it prevents the surface from drying out too early while baking, resulting in a better oven spring. Furthermore the moist air condenses on the cold surface of the dough which improves gelatinization of the starch. This in turn gives better crust formation. After 10 min at 250 °C I open the oven to let the moisture out, take out the dish with water, turn the heat down to 220 °C and close the oven door. I bake the breads to a core temperature of about 93-95 °C.</p>
<p><a href="http://blog.khymos.org/wp-content/2009/09/sd-bread-2.jpg"><img src="http://blog.khymos.org/wp-content/2009/09/sd-bread-2.jpg" alt="sd-bread-2" title="sd-bread-2" width="620" height="620" class="alignnone size-full wp-image-1793" /></a><br />
<em>Here I bake two 800 g loaves on a baking stone. Notice the dish with water for steam generation.</em></p>
<p>I should comment on mixing. When kneading by hand I&#8217;ve had a tendency to add to much flour. In fact I think this is one of the reasons why I quit baking bread several years ago &#8211; I found that the breads I made generally were a little to dry with a poor crumb, and at that time I didn&#8217;t really sit down and think about these matters. In retrospect however there&#8217;s no doubt that baking bread and adding flour <em>ad lib</em> until the dough <em>feels</em> good to touch is NOT recommended. Well anayway not unless you stop adding flour while the dough is still quite sticky. The thing about doughs with a high percentage rye is that they are quite sticky, and they should be. <strong>This is the best argument you&#8217;ll ever get for buying a kitchen gadget: bread doughs are too sticky to be kneaded by hand!</strong> There you have it! I&#8217;ve settled with the <a href="http://www.assistent-original.se/website2/1.0.2.0/2/2/">Assistent</a> from Sweden. It was formerly sold under the Electrolux brand, but is now marketed indepentendly, yet it is still produced at the very same factory as always. In the US the machine is known as the <a href="http://www.amazon.com/exec/obidos/ASIN/B00006WNNH/kjemiihverdao-20">Magic</a> <a href="http://www.amazon.com/exec/obidos/ASIN/B0006DOQWY/kjemiihverdao-20">Mill</a>. It has a huge 7 L bowl that rotates. The roller is attached to a flexible arm, so if the dough is to hard to work the arm just moves to the middle of the bowl. This significantly reduces the chances of overheating the motor. There are of course other alternatives from <a href="http://www.amazon.com/exec/obidos/ASIN/B00156E2NO/kjemiihverdao-20">Kitchen Aid</a>, <a href="http://www.amazon.com/exec/obidos/ASIN/B00015NMX6/kjemiihverdao-20">Hamilton Beach</a> and <a href="http://www.amazon.com/exec/obidos/ASIN/B0013FA5YW/kjemiihverdao-20">Viking Range</a> which seem robust, but I have no experience with these. However, I doubt that the average Kenwood can cope with more than 3 kg of bread dough (but please correct me if I&#8217;m wrong <img src='http://blog.khymos.org/wp-includes/images/smilies/icon_smile.gif' alt=':)' class='wp-smiley' /> ).</p>
<p><a href="http://blog.khymos.org/wp-content/2009/09/sd-dough.jpg"><img src="http://blog.khymos.org/wp-content/2009/09/sd-dough.jpg" alt="sd-dough" title="sd-dough" width="620" height="620" class="alignright size-full wp-image-1794" /></a><br />
<em>Unlike most other machines, the bowl of the Magic Mill/Assitent rotates while the roller pushes the dough to the sides of the bowl</em></p>
<p><strong>Sources for further reading</strong></p>
<p>I&#8217;ve read quite a bit about sourdoughs, and what I&#8217;ve been looking for a simple correlation between temperature, hydration and fermentation time. An excellent source of information with lots of practical advice is the <a href="http://www.nyx.net/~dgreenw/sourdoughqa.html">FAQ</a> from <a href="http://groups.google.com/group/rec.food.sourdough/topics?hl=en&#038;lnk">rec.food.sourdough</a>. </p>
<p>I think the best resource I&#8217;ve found sofar is Lorenz and Bruemmer&#8217;s chapter &#8220;Preferments and Sourdoughs for German Breads&#8221; and Teija-Tuula Valjakka, Heikki Kerojoki and Kati Katina&#8217;s chapter &#8220;Sourdough Bread in Finland and Eastern Europe&#8221; in <a href="http://www.amazon.com/exec/obidos/ASIN/0824742648/kjemiihverdao-20">&#8220;The handbook of dough fermentations&#8221;</a>. I will have to study these more carefuly. </p>
<p>There are quite a number of academic publications which also touch upon the effect of temperature on acid development. Here are some snippets:</p>
<p><a href="http://dx.doi.org/10.1007/BF01202806">&#8220;Controlled production of acetic acid in wheat sour doughs&#8221;</a>:</p>
<blockquote><p>&#8230;temperature has no significant effect, and that fructose is more efficient in influencing the FQ than dough yield.</p></blockquote>
<p>FQ = fermentation quotient = lactic acid / acetic acid</p>
<p><a href="http://dx.doi.org/10.1016/S0740-0020(95)80134-0">&#8220;Volatile compound and organic acid productions by mixed wheat sour dough starters: Influence of fermentation parameters and dynamics during baking&#8221;</a>:</p>
<blockquote><p>&#8230; Low temperature (25 degrees C) and sour dough firmness (dough yield 135) were appropriate for LAB souring activities but limited yeast metabolism. Raising the temperature to 30 degrees C and semi-fluid sour doughs gave more complete volatile profiles &#8230;</p></blockquote>
<p><a href="http://www.google.com/url?sa=t&amp;source=web&amp;ct=res&amp;cd=1&amp;url=http%3A%2F%2Fethesis.helsinki.fi%2Fjulkaisut%2Fmaa%2Felint%2Fvk%2Fkatina%2Fsourdoug.pdf&amp;ei=ZRcTSuqTNtnx_AaNz62xDw&amp;usg=AFQjCNEgIJnbS52k-s-fAH5HlQ2m0U92_w&amp;sig2=g8aMqRKvgBoVEskq4aKoVg">&#8220;Sourdough: a tool for the improved flavour, texture and shelf-life of wheat bread&#8221;</a> (Ph.D. thesis of Kati Katina):</p>
<blockquote><p>The production of acids depends also on other things such as fermentation temperature, time and dough yield. Optimum temperatures for the growth of lactobacilli are 30-40 °C depending on strain (Stanier et al. 1987) and for yeasts 25-27 °C. In general, a higher temperature, a higher water content of sourdough and the utilisation of wholemeal flour enhances the production of acids in wheat sourdoughs (Brummer and Lorenz 1991, Lorenz and Brummer 2003).</p></blockquote>
<p>I must admit that I&#8217;m a little confused as some of these snippets seem to contradict. It might be that I&#8217;m overlooking something important though and that I&#8217;m taking results out of their context. Any insight from my readers on this will be greatly appreciated!</p>
<p><strong>Starter details</strong><br />
Here&#8217;s the details from my notebook on how I fed my sourdough starter. As I mentioned above, I wonder if discarding dough in the process actually does make sense after all.</p>
<ul>
<li>July 29, evening: 50 g rye + 50 g water</li>
<li>July 30, morning: 25 g rye + 25 g water, evening: small bubbles (!), 50 g rye + 50 g water</li>
<li>July 31, morning: 50 g rye + 50 g water, evening: pH measured to 3-4 with strips, fed with 50 g rye + 50 g water</li>
<li>August 1:  morning: 50 g rye + 50 g water, tested for bread baking, result: not active enough, feeding continued evening: 50 g rye + 50 g water</li>
<li>August 2: morning: 50 g rye + 50 g water, evening 50 g rye + 50 g water</li>
<li>August 3: morning: 50 g rye + 50 g water, evening: no bubbles, <strong>discarded all except ~100 g</strong>, fed with 50 g rye + 50 g water</li>
<li>August 4: morning: 50 g rye + 50 g water, evening 50 g rye + 50 g water</li>
<li>August 5: morning: 50 g rye + 50 g water, evening: big bubbles, <strong>the starter is active</strong>, CO2 production evidenced by tickling in nose,  fed with 60 g rye + 60 g water and 2 x 100 g samples taken for fridge and freezer as fallback points</li>
<li>August 6: morning: 50 g rye + 50 g water, first successfull bread made with the starter</li>
</ul>
<p>I show my raw data to illustrate that it&#8217;s not straightforward, even with temperature control. </p>
<p><strong>A fool proof starter &#8211; is it possible?</strong><br />
What I&#8217;m hoping to achieve can be summarized as follows: A &#8220;fool proof&#8221;, robust and quick method to obtain a sourdough starter that&#8217;s as simple as possible, using only flour and water (possibly with addition of some fruit) without having to waste anything of the starter. Temperature is maintained using a thermostated water bath. Preferably it should be possible to adjust the fermentation quotient (ratio of lactic acid/acetic acid) and the total titrable acid content by means of temperature, time and hydration/dough yield.</p>
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		<title>Sourdough work in progress (part I)</title>
		<link>http://blog.khymos.org/2009/05/21/sourdough-work-in-progress-part-i/</link>
		<comments>http://blog.khymos.org/2009/05/21/sourdough-work-in-progress-part-i/#comments</comments>
		<pubDate>Thu, 21 May 2009 12:28:47 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[blogs]]></category>
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		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[bread]]></category>
		<category><![CDATA[carbon dioxide]]></category>
		<category><![CDATA[CO2]]></category>
		<category><![CDATA[failed experiment]]></category>
		<category><![CDATA[fermentation]]></category>
		<category><![CDATA[immersion circulator]]></category>
		<category><![CDATA[sourdough]]></category>
		<category><![CDATA[temperature]]></category>
		<category><![CDATA[thermostat]]></category>
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		<category><![CDATA[wild yeast]]></category>
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		<guid isPermaLink="false">http://blog.khymos.org/?p=1590</guid>
		<description><![CDATA[Attempt to make a sourdough starter using dried apricots, using my immersion circulator for temperature control. I got some bubbling yeast activity, but the final bread dough never rose properly. Inspired by the Swedish bread blog Pain de Martin which I recently discovered I decided it was time to have a go at sourdough breads! [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2009/05/apricot-starter.jpg" alt="apricot-starter" title="apricot-starter" width="620" height="620" class="alignnone size-full wp-image-1643" /><br />
<em>Attempt to make a sourdough starter using dried apricots, using my immersion circulator for temperature control. I got some bubbling yeast activity, but the final bread dough  never rose properly.</em></p>
<p>Inspired by the Swedish bread blog <a href="http://paindemartin.blogspot.com/">Pain de Martin</a> which I recently discovered I decided it was time to have a go at sourdough breads! Although one of my favorite types of bread it&#8217;s a long time since I gave it a try and even longer since I actually succeeded. Leaving apple peel covered with water for two weeks in a cool place (15 °C) I got a light apple cider which I used to make a starter some years ago. I followed a recipe from the Norwegian artisan bakery <a href="http://www.apentbakeri.no/">Åpent bakeri</a> and it gave a marvelous bread. But since then I&#8217;ve tried to repeat this twice without success. No wonder that even Rose Levy Beranbaum in her book <a href="http://www.amazon.com/exec/obidos/ASIN/0393057941/kjemiihverdao-20">&#8220;The Bread Bible&#8221;</a> writes that she didn&#8217;t intend to include a chapter on sourdough at all. There&#8217;s no doubt that <strong>sourdoughs are tricky</strong>, but I was a litte surprised and disappointed that someone who sets of to write a 600+ page book on bread even considered to skip sourdough&#8230; Luckily she changed her mind and the introduction has a fascinating nice-to-know fact: 1 g flour contains about 320 lactic acid bacteria and 13000 yeast cells!</p>
<p>I believe one the reasons why sourdoughs seem to live their own lifes sometimes is that they need to be kept in a warm place. My kitchen isn&#8217;t that warm so <strong>I figured it was time to use my immersion circulator and give sourdough another chance</strong> (who says you can only use immersion circulators for sous vide anyway? &#8211; I think my next project will be to make yoghurt!). With a thermostated water bath keeping a sourdough starter at constant temperature is as easy as 1-2-3. But surprisingly I haven&#8217;t seen any blogposts yet from people using their sous vide water baths for sourdough starters (although some have built their own water baths for this purpose using <a href="http://samartha.net/SD/procedures/DM3/index.html#SEC3">aquarium equipment</a>).<br />
<span id="more-1590"></span><br />
<img src="http://blog.khymos.org/wp-content/2009/05/apple-starter.jpg" alt="apple-starter" title="apple-starter" width="620" height="620" class="alignnone size-full wp-image-1646" /><br />
<em>Fresh apple peel in water. This particular experiment failed &#8211; the cider smelled OK, but there was quite a lot of mould on the surface after two weeks so I didn&#8217;t dare to proceed &#8230;</em></p>
<p>It was Martin&#8217;s post on an <a href="http://paindemartin.blogspot.com/2007/09/explosivt-surdegsbak.html">apricot starter</a> that triggered my desire for sourdough (but careful &#8211; never close your jar with a rubber as shown in his picture!). I got a bag of dried apricots and gave it a try. There was some bubbling and it smelled quite nice, but the bread dough never rose properly. I later found out that in a comment to the first post and a <a href="http://paindemartin.blogspot.com/2008/02/vildjst-p-aprikos.html">later post on the same topic</a> it was pointed out that the apricots should not be treated with sulfur dioxide or a sulfite (used to conserve the fruit, appears on labels as E220-228 in Europe). That&#8217;s very obvious once you think about it, because <strong>the sulfur dioxide/sulfite is there to kill microogranisms and increase shelf life</strong>. For a sourdough however you want living microorganisms! The solution to this is to use untreated dried apricots. I haven&#8217;t been able to find any yet, but I&#8217;ll definitely give it a new try once I find some! Other options of course are to use dried or fresh apples, pears, grapes &#8211; preferably not treated with pesticides or sulfur dioxide &#8211; as the surface of these fruits are host to many yeasts.</p>
<p><img src="http://blog.khymos.org/wp-content/2009/05/rye-starter_firm.jpg" alt="rye-starter_firm" title="rye-starter_firm" width="620" height="310" class="alignnone size-full wp-image-1645" /><br />
<em>A relatively firm rye starter with 150 g water and 200 g whole grain rye flour (left) shows signs of yeast activity after 24h at 28 °C (right).</em></p>
<p>Having failed with the apricot starter I decided to give a traditional rye sourdough a try, using a recipe from the book <a href="http://www.cappelendamm.no/main/Katalog.aspx?f=1006&#038;isbn=9788202249052">&#8220;Brød&#8221;</a> (=bread) by <a href="http://www.apentbakeri.no/">&#8220;Åpent bakeri&#8221;</a>. I got a nice bubbling after 1 day, but the starter was pretty dry. As I discarded a portion and fed more flour and water to the starter it seemd as if it died&#8230; I (believe) I followed the recipe very accurately (except for the very first day where I opted for a hydration of 75% instead of 60%), but the final dough never rose, so I had to cheat and add bakers yeast in order to actually get the breads baked. Acid production was fine however and the resulting <strong>flavor was very delicious</strong> and I got the crumb that I desired! However, with all these problems I figured it was time to turn to the scientific litterature and read more on sourdouhs &#8230; More on what I found out in a follow up post.</p>
<p>One last thing: Despite my limited experience with sourdoughs I&#8217;ve already been a little annoyed by recipes for starters that require one to discard a significant portion of the sourdough every day before feeding the start with more water and flour. One obvious way around would be to start at a much smaller scale so that every feeding can be done without having to waste any sourdough. In fact Kurt Janz already has a post with <a href="http://samartha.net/SD/MakeStarter01.html">detailed instructions</a> on a <strong>less wasteful sourdough</strong> (and he BTW has <a href="http://samartha.net/SD/">one of the most comprehensive sites on sourdough</a> I&#8217;m aware of including a <a href="http://samartha.net/SD/SDcalc04.html">sourdough calculator</a>). The only reason I could think of why one perhaps would want to use more than a couple grams of flour to start with would be to outnumber any unwanted yeasts or bacteria from the air or the equipment. Is this the case? Are there any other reasons? To circumvent this one would simple have to work very clean and wash all equipment properly. </p>
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		<title>Cherry jams with a twist</title>
		<link>http://blog.khymos.org/2008/08/03/cherry-jams-with-a-twist/</link>
		<comments>http://blog.khymos.org/2008/08/03/cherry-jams-with-a-twist/#comments</comments>
		<pubDate>Sat, 02 Aug 2008 23:16:04 +0000</pubDate>
		<dc:creator>Martin Lersch</dc:creator>
				<category><![CDATA[hydrocolloids]]></category>
		<category><![CDATA[molecular gastronomy]]></category>
		<category><![CDATA[recipe]]></category>
		<category><![CDATA[anis]]></category>
		<category><![CDATA[canning]]></category>
		<category><![CDATA[cherries]]></category>
		<category><![CDATA[cherry]]></category>
		<category><![CDATA[cloves]]></category>
		<category><![CDATA[condensation]]></category>
		<category><![CDATA[depitting]]></category>
		<category><![CDATA[fungi]]></category>
		<category><![CDATA[gelling]]></category>
		<category><![CDATA[ginger]]></category>
		<category><![CDATA[herrenmarmelade]]></category>
		<category><![CDATA[hyphae]]></category>
		<category><![CDATA[jam]]></category>
		<category><![CDATA[kirschen]]></category>
		<category><![CDATA[kirschenmus]]></category>
		<category><![CDATA[lids]]></category>
		<category><![CDATA[marmelade]]></category>
		<category><![CDATA[mold]]></category>
		<category><![CDATA[myths]]></category>
		<category><![CDATA[pectin]]></category>
		<category><![CDATA[pepper]]></category>
		<category><![CDATA[peppermint]]></category>
		<category><![CDATA[pH]]></category>
		<category><![CDATA[star anis]]></category>
		<category><![CDATA[sterilization]]></category>
		<category><![CDATA[stoning]]></category>
		<category><![CDATA[water activity]]></category>
		<category><![CDATA[yeast]]></category>

		<guid isPermaLink="false">http://blog.khymos.org/?p=450</guid>
		<description><![CDATA[We have a small garden with a single tree. It&#8217;s a sweet cherry tree and this year must have been one of the best ever. In May it was overthrown with flowers. Last year I made some jam which came out OK, but the drawback with sweet cherries is that their taste doesn&#8217;t really compare [...]]]></description>
			<content:encoded><![CDATA[<p><img src="http://blog.khymos.org/wp-content/2008/08/cherry-blossom-1.jpg" alt="" title="cherry-blossom-1" width="450" height="450" class="alignnone size-full wp-image-458" /></p>
<p>We have a small garden with a single tree. It&#8217;s a sweet cherry tree and this year must have been one of the best ever. In May it was overthrown with flowers. Last year I made some jam which came out OK, but the drawback with sweet cherries is that their taste doesn&#8217;t really compare with that of sour cherries. They&#8217;re good to eat, but not as good for cooking and jam as their sour cousins. The summer last year was quite wet and cold which could explain the fad taste, but this year however has been quite hot and the cherries grew <strong>darker and sweeter</strong> as summer proceeded.</p>
<p><img src="http://blog.khymos.org/wp-content/2008/08/cherry-blossom-4.jpg" alt="" title="cherry-blossom-4" width="450" height="450" class="alignnone size-full wp-image-461" /></p>
<p>I decided to give cherry jam another try. To improve the flavor even further, I was pondering on <strong>adding spices</strong>. My mom has previously added cloves and cinnamon to plums when making jam. The first place I looked was under <em>cherries</em> in the book <a href="http://www.amazon.com/exec/obidos/ASIN/0471287857/kjemiihverdao-20">&#8220;Culinary artistry&#8221;</a>. Among the numerous suggestions for flavor pairings it was <strong>black pepper</strong> and <strong>lemon</strong> that caught my attention. Who would have thought? I made a small test batch and was quite pleased by the &#8220;bite&#8221; provided by pepper so I proceeded with a full batch. I used a pre-mixed gelling sugar from <a href="http://www.retail.daniscosugar.co.uk/cms/resources/file/eb68c84376c6432/10.pdf">Danisco sugar</a> (which contained sugar, pectin, a preservative and an acid), but you could use whatever pectin you have at hand. Just follow the instructions on the pack (more on the science further down).</p>
<p><img src="http://blog.khymos.org/wp-content/2008/08/cherry-blossom-3.jpg" alt="" title="cherry-blossom-3" width="450" height="450" class="alignnone size-full wp-image-460" /></p>
<p>Having added pepper and a little of the sugar to get an idea of how it would turn out, it almost felt as if ginger was already there so I added a little more to accentuate that. The other spices were added to round everything off. The pepper taste is quite noticeable if you eat the jam by itself, but <strong>on buttered bread or toast it&#8217;s really nice</strong>. I also suggest that you try it with different semi-soft and hard cheeses such as <a href="http://en.wikipedia.org/wiki/Emmentaler">Emmentaler</a>, <a href="http://en.wikipedia.org/wiki/Jarlsberg_cheese">Jarlsberg</a>, <a href="http://en.wikipedia.org/wiki/Prästost">Prästost</a>, <a href="http://en.wikipedia.org/wiki/Parmesan">Parmesan</a> or <a href="http://en.wikipedia.org/wiki/Pecorino">Pecorino</a>. My wife thinks it&#8217;s a little to much pepper, but for me it&#8217;s just perfect. In German this jam would be known as a <em>Herrenmarmelade</em> (a gentleman&#8217;s jam). If you&#8217;re not very fond of pepper however it&#8217;s a good idea to start with half the amount of pepper.</p>
<p><strong>Spicy cherry jam with pepper</strong><br />
3.7 kg depitted sweet cherries<br />
7.0 g black pepper, ground<br />
0.8 g cloves, ground<br />
0.7 g ginger, ground<br />
1.3 g anis seeds, ground<br />
0.8 g star anis, ground<br />
zest and juice from 1/2 lemon<br />
2.2 kg gelling sugar (with pectin and preservative)</p>
<p>Place enough jars in a <em>cold</em> oven and heat to 120-130 °C to sterilize them (this is more convenient than in boiling water). Depit cherries (conveniently done <a href="http://www.amazon.com/exec/obidos/ASIN/B000A3880G/kjemiihverdao-20">with</a> <a href="http://www.amazon.com/exec/obidos/ASIN/B00068S2V0/kjemiihverdao-20">a</a> <a href="http://www.amazon.com/exec/obidos/ASIN/B0013DZZSA/kjemiihverdao-20">cherry</a> <a href="http://www.amazon.com/exec/obidos/ASIN/B001CDS59W/kjemiihverdao-20">stoner</a>) and cut in four (helps you discover those stones that eluded the cherry stoner). Add spices and bring to boil. Remove any remaining pits that float up to the surface. Pureé with immersion blender (hopefully you will not hear the sound of cherry pits being crushed at this stage). Add gelling sugar. Let boil and skim of foam. Fill the hot jars immediately. And remember &#8211;  as all chemists know &#8211; <strong>hot glass looks just like cold glass</strong>! Use a <a href="http://www.amazon.com/exec/obidos/ASIN/B00004UE88/kjemiihverdao-20">canning</a> <a href="http://www.amazon.com/exec/obidos/ASIN/B00009PGUR/kjemiihverdao-20">funnel</a> to avoid spilling jam on the sealing surface of the jars. Leave to cool for 10-15 minutes and then screw on lids. I usually wipe the inside of the lids with 40-60% alcohol and then screw them on tightly before the alcohol has evaporated. There&#8217;s more at the end regarding the procedure for closing the jars.</p>
<p>This way of canning is very convenient and the jam will keep for several years in closed jars if kept in a cool, dark and dry place. This is due to the high sugar concentration (sugar binds water, and unless water is available, molds won&#8217;t grow), the low pH and &#8211; if added &#8211; the presence of preservatives. A more tedious way is to sterilize the jars after filling by boiling in water. This is no doubt the best way to sterilize the jars, but for jams with a high sugar content and a low pH it&#8217;s a little <strong>overkill</strong>. The <a href="http://www.uga.edu/nchfp/how/can7_jam_jelly.html">National Center for Home Food Preservation</a> in the US has more information about this (but notice that there are different traditions &#8211; I wonder if there is a <strong>divide between Europe and North America?</strong>). There are also many books about this and good place to start would be the <a href="http://www.amazon.com/exec/obidos/ASIN/0972753702/kjemiihverdao-20">&#8220;Ball Blue Book of Preserving&#8221;</a>, better known as BBB among home canners. If you chose this method you should probably use a little more pectin as the additional heating at low pH will degrade some of the pectin making the jam more runny.</p>
<p><img src="http://blog.khymos.org/wp-content/2008/08/cherry-blossom-2.jpg" alt="" title="cherry-blossom-2" width="450" height="450" class="alignnone size-full wp-image-459" /></p>
<p>Using black pepper in a jam worked really well so I googled this and found Clotilde&#8217;s recipe for a <a href="http://chocolateandzucchini.com/archives/2004/05/strawberry_jam_with_black_pepper_and_fresh_mint.php">strawberry jam with pepper and peppermint</a>. She got it from Christine Ferber, author of <a href="http://www.amazon.com/exec/obidos/ASIN/0870136291/kjemiihverdao-20">&#8220;Mes confitures: The Jams and Jellies of Christine Ferber&#8221;</a> which has recipes organized according to season. As mint was also mentioned as a good flavor pairing for cherries in <a href="http://www.amazon.com/exec/obidos/ASIN/0471287857/kjemiihverdao-20">&#8220;Culinary artistry&#8221;</a> I thought I&#8217;d give pepper and peppermint a try.</p>
<p><strong>Cherry jam with pepper and peppermint</strong><br />
2.2 kg depitted sweet cherries<br />
1.3 kg sugar<br />
2.4 g fresh peppermint leaves<br />
2.8 g black pepper, ground<br />
zest and juice of 1/2 lemon<br />
1 pack of Certo fruit pectin*</p>
<p>Depit cherries and cut in four. Add pepper and peppermint and bring to boil. Remove any remaining pits that float up to the surface. Pureé with immersion blender. Add pectin and stir until dissolved. Add sugar. Let boil and skim off foam. Sterilize and fill jars as in the previous recipe.</p>
<p>[ * The Certo pack weighs 70 g and contains sugar (for easier dispersion of the pectin), citrus pectin, citric acid to get the right pH for gelling and a preservative (ascorbic acid). ]</p>
<p>This jam was dominated by peppermint and the pepper could barely be noticed. I found it very refreshing and there is a <strong>surprise element</strong> as the red color does not suggest the presence of peppermint. Apart from the obvious use as a bread spread, I can imagine that this jam would be very nice with roasted meat, especially lamb, reindeer, elk and perhaps also wild game.</p>
<p>Having experimented with different spices and peppermint, my wife asked me to also make a batch of plain cherry jam which I happily did. But next year I would like to try making <a href="http://realjam-recipes.net/jam-and-jelly/jam-recipes/cherry-jam-with-red-wine/">cherry jam with red wine</a>!</p>
<p><img src="http://blog.khymos.org/wp-content/2008/08/cherry-jars.jpg" alt="" title="cherry-jars" width="450" height="450" class="alignnone size-full wp-image-457" /></p>
<p>As you can imagine, I couldn&#8217;t do all this without offering <strong>the chemistry behind</strong> some thoughts. Pectin chemistry is quite complicated though and there are several types available (low methoxyl, high methoxyl and amidated &#8211; so far I&#8217;ve only included the two first in <a href="http://khymos.org/recipe-collection.php">&#8220;Texture &#8211; A hydrocolloid recipe collection&#8221;</a>). Commercial packs of pectin for home use do normally not specify which type of pectin they contain, but I assume that it is the high methoxyl which gels in the presence of sugar and at low pH (as opposed to the low methoxyl which requires calcium ions to gel). The easiest is probably to follow the instructions that come with the pack you chose. Always <strong>add pectin before you add sugar</strong> (unless you premix them). The reason for this is that the gelling of high methoxyl pectins is promoted by sugar. If you add sugar before pectin, it will be very diffult to get the pectin properly dispersed and dissolved (it can be done with an immersion blender though &#8211; I&#8217;ve tried that once). Ready to use pectin is often pre-mixed with an acid to get the pH below 3.5 which promotes gelling. Citric acid is often used, and plain lemon juice will also do the job. Lowering the pH is especially important when using ripe or over ripe fruit as these can be less acidic and also contain less pectin if we are talking about pectin containing fruit. After the pectin and sugar have been added, the jam shouldn&#8217;t boil for more than a couple of minutes as pectin is not very heat stable.</p>
<p>There are also a couple of claims found in jam recipes which I have been wondering about:</p>
<p><strong>Skimming:</strong> Almost all recipes I have seen for jams call for rapid skimming of the foam which formes when the jam mixture boils. One explanation I&#8217;ve seen is that this is done to prevent growth of mold, as these apparently grow more easily in the foam. There are certainly airborn molds, but the bubbles in the foam come from the jam as it boils, so it&#8217;s been very hot and presumably sterilized. So I&#8217;m simply wondering if the whole skimming is about esthetics &#8211; which is is still a good enough reason to me (but then I wish the recipes could state that!).</p>
<p><strong>Turning jars upside-down:</strong> One thing that has puzzled me for a time is why recipes recommend that the jars should be turned upside-down. I&#8217;ve googled and checked several books and have come up with a couple of explanations (but most recipes only state that it should or shouldn&#8217;t (!) be done, without giving any reason). The fun thing is that the suggested time for how long the jars should remain turned upside-down varies from 2 minutes to several hours when the jam is cool and has set.</p>
<ul>
<li>One site claims it is done to <a href="http://www.recipezaar.com/bb/viewtopic.zsp?t=268316&#038;sid=e46aa1c7788617654610e2b8ac0e3c5c">prevent larger pieces of fruit from settling to the bottom</a>. This does make sense, and in that case there is no reason to do it if the fruit has been puréed.</li>
<li>A blogpost commenter suggests that turning the jars upside-down for 5 minutes <a href="http://mooseyard.com/Jens/2007/07/apricot-jam-recipe/">makes sure the inside of the lid gets sterilized too</a>. The temperature of the jam at this time is probably somewhere around 95 °C, so it does seem reasonable that it might kill some molds residing on the lid. I&#8217;d give this a thumbs up. Any microbiologist who could confirm this?</li>
<li>Personally I have speculated whether turning the jars upside-down would allow water (or jam to be precise) to be drawn into the seal by <a href="http://en.wikipedia.org/wiki/Capillary_action">capillary action</a> and that this helps to make a perfect seal, but <a href="http://www.fcs.uga.edu/pubs/current/FDNS-E-37-1.html">several</a> <a href="http://www.ext.vt.edu/news/releases/082505/canningjars.html">sites</a> emphasize that this should not be done to prevent the seal from being broken (these sites assume that a canner has been used &#8211; i.e. sterilizing the filled jars with lids in boiling water for 5 to 10 min). I&#8217;m not sure, but I wonder if there is a difference here  between screw caps and glass lids with rubber bands?</li>
<li>A last reason to turn jars upside down would be to prevent the water evaporating from the hot jam to condensate on the lid. If the jars are left to cool upside-down for 10-15 minutes, but turned back before the jam sets this will prevent water to condense on the lid and drip back to the surface of the jam. This water could potentially mean better conditions for growth of molds. This theory is also supported by the suggestion found in old cookbooks where the jars are left to cool completely without lids to let the surface dry and form a skin, and then covered with a filter paper dipped in alcohol before tying them up with pergament paper and string.</li>
</ul>
<p>The <strong>conclusion so far regarding turning the jars upside-down</strong> can be summed up as follows. You should chose of the three methods:</p>
<ul>
<li>Cover with lid immediately and turn upside-down until cool enough to handle (~40-50 °C). Then return to upright position. This will prevent condensation of water on the lid, it might help create a better seal and it could possibly knock out some molds on the lid. The jam however will most likely not have set yet.</li>
<li>As above, with the only difference that you leave the jars upside-down until cool and set. This means that the air pocket will not be below the lid but at the bottom of the glass when turned back to the upright position.</li>
<li>Allow the jam too cool without lids until a skin has formed and the jars are cool enough to handle. This prevents condensation of water on the lid. Wipe the inside of the lids with the highest percentage alcohol available (but do NOT use denatured alcohol!) &#8211; typically it would be 40% or 60% &#8211; and screw on the lid before the alcohol evaporates. The skin formed will be less suceptible to growth of mold because there is less water present and because of the presence of alcohol.</li>
</ul>
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